TY - JOUR
T1 - Solubility of 4-methylsulfonylacetophenone in nine pure solvents and (ethyl acetate + n-hexane) binary solvent mixtures from 278.15 K to 328.15 K
AU - Hao, Jianfeng
AU - Yang, Wenge
AU - Li, Hongjie
AU - Fan, Shimin
AU - Zhao, Wangdan
AU - Hu, Yonghong
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2017/1
Y1 - 2017/1
N2 - We focus on the solubility of 4-methylsulfonylacetophenone. A gravimetric method was taken to measure the solubility of 4-methylsulfonylacetophenone in n-hexane, ethyl acetate, methanol, ethanol, n-propyl alcohol, n-butyl alcohol, ethylene glycol, cyclohexane, isobutyl alcohol, and (ethyl acetate + nhexane) binary solvent mixtures from 278.15 K to 328.15 K under atmospheric pressure. Its corresponding (solid + liquid) equilibrium results will provide essential support for further theoretical studies. The solubility of 4-methylsulfonylacetophenone in nine pure solvents were correlated with λh and Apelblat models, while 4-methylsulfonylacetophenone in (ethyl acetate + nhexane) binary solvent mixtures were correlated with the Apelblat and CNIBS/ R-K models. The Apelblat model was proven to be the best-fit model for correlating the solubility of both pure solvents and binary solvents mixtures from the analysis of the STATISTIC.
AB - We focus on the solubility of 4-methylsulfonylacetophenone. A gravimetric method was taken to measure the solubility of 4-methylsulfonylacetophenone in n-hexane, ethyl acetate, methanol, ethanol, n-propyl alcohol, n-butyl alcohol, ethylene glycol, cyclohexane, isobutyl alcohol, and (ethyl acetate + nhexane) binary solvent mixtures from 278.15 K to 328.15 K under atmospheric pressure. Its corresponding (solid + liquid) equilibrium results will provide essential support for further theoretical studies. The solubility of 4-methylsulfonylacetophenone in nine pure solvents were correlated with λh and Apelblat models, while 4-methylsulfonylacetophenone in (ethyl acetate + nhexane) binary solvent mixtures were correlated with the Apelblat and CNIBS/ R-K models. The Apelblat model was proven to be the best-fit model for correlating the solubility of both pure solvents and binary solvents mixtures from the analysis of the STATISTIC.
UR - http://www.scopus.com/inward/record.url?scp=85031325015&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.6b00617
DO - 10.1021/acs.jced.6b00617
M3 - 文章
AN - SCOPUS:85031325015
SN - 0021-9568
VL - 62
SP - 236
EP - 242
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 1
ER -