Solvent-free synthesis of 1, 1'-bi-2-naphthanol by ball milling

Mei Hong Jin; Guo Wei Song; Liang Wang; Zhen Jiang Li

Solvent-free synthesis of 1, 1'-bi-2-naphthanol by ball milling

Mei Hong Jin, Guo Wei Song, Liang Wang, Zhen Jiang Li

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

Abstract

1, 1'-Bi-2-naphthanol is prepared with yield of 91% by the coupling of β-naphthol under solvent-free condition in ball mill using CuCl₂·2H₂O as an oxidant. The optimum conditions are given as follows: 1:12 of the ratio of CuCl₂·2H₂O and β-naphthol by molar and 350 r/min of the rotational speed of the ball mill for 2 hours. The effect of other oxidants of Cu(II)/Fe(III) on the coupling of β-naphthol is investigated as well. The chemical structure of the product is characterized by IR and 1H-NMR.

Original language	English
Pages (from-to)	35-37
Number of pages	3
Journal	Xiandai Huagong/Modern Chemical Industry
Volume	31
Issue number	6
State	Published - Jun 2011

Keywords

1, 1'-bi-2-naphthanol
Ball mill
Mechanochemistry
Oxidative coupling
Solvent-free

Cite this

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title = "Solvent-free synthesis of 1, 1'-bi-2-naphthanol by ball milling",

abstract = "1, 1'-Bi-2-naphthanol is prepared with yield of 91% by the coupling of β-naphthol under solvent-free condition in ball mill using CuCl2·2H2O as an oxidant. The optimum conditions are given as follows: 1:12 of the ratio of CuCl2·2H2O and β-naphthol by molar and 350 r/min of the rotational speed of the ball mill for 2 hours. The effect of other oxidants of Cu(II)/Fe(III) on the coupling of β-naphthol is investigated as well. The chemical structure of the product is characterized by IR and 1H-NMR.",

keywords = "1, 1'-bi-2-naphthanol, Ball mill, Mechanochemistry, Oxidative coupling, Solvent-free",

author = "Jin, {Mei Hong} and Song, {Guo Wei} and Liang Wang and Li, {Zhen Jiang}",

year = "2011",

month = jun,

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volume = "31",

pages = "35--37",

journal = "Xiandai Huagong/Modern Chemical Industry",

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T1 - Solvent-free synthesis of 1, 1'-bi-2-naphthanol by ball milling

AU - Jin, Mei Hong

AU - Song, Guo Wei

AU - Wang, Liang

AU - Li, Zhen Jiang

PY - 2011/6

Y1 - 2011/6

N2 - 1, 1'-Bi-2-naphthanol is prepared with yield of 91% by the coupling of β-naphthol under solvent-free condition in ball mill using CuCl2·2H2O as an oxidant. The optimum conditions are given as follows: 1:12 of the ratio of CuCl2·2H2O and β-naphthol by molar and 350 r/min of the rotational speed of the ball mill for 2 hours. The effect of other oxidants of Cu(II)/Fe(III) on the coupling of β-naphthol is investigated as well. The chemical structure of the product is characterized by IR and 1H-NMR.

AB - 1, 1'-Bi-2-naphthanol is prepared with yield of 91% by the coupling of β-naphthol under solvent-free condition in ball mill using CuCl2·2H2O as an oxidant. The optimum conditions are given as follows: 1:12 of the ratio of CuCl2·2H2O and β-naphthol by molar and 350 r/min of the rotational speed of the ball mill for 2 hours. The effect of other oxidants of Cu(II)/Fe(III) on the coupling of β-naphthol is investigated as well. The chemical structure of the product is characterized by IR and 1H-NMR.

KW - 1, 1'-bi-2-naphthanol

KW - Ball mill

KW - Mechanochemistry

KW - Oxidative coupling

KW - Solvent-free

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M3 - 文章

AN - SCOPUS:79960136325

SN - 0253-4320

VL - 31

SP - 35

EP - 37

JO - Xiandai Huagong/Modern Chemical Industry

JF - Xiandai Huagong/Modern Chemical Industry

IS - 6

ER -

Solvent-free synthesis of 1, 1'-bi-2-naphthanol by ball milling

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