Solvothermal synthesis, crystal structure and magnetic properties of the one-dimensional coordination polymer Ni(DMBDIZ)(OOCMe)2 (DMBDIZ = 2,6-dimethylbenzo[1,2-d:4,5-d′]diimidazole)

Chen Xin Cai; Yun Qi Tian; Xiao Ming Ren; Yi Zhi Li; Xiao Zeng You

doi:10.1023/A:1022996703047

Solvothermal synthesis, crystal structure and magnetic properties of the one-dimensional coordination polymer Ni(DMBDIZ)(OOCMe)₂ (DMBDIZ = 2,6-dimethylbenzo[1,2-d:4,5-d′]diimidazole)

Chen Xin Cai, Yun Qi Tian, Xiao Ming Ren, Yi Zhi Li, Xiao Zeng You

Nanjing University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The solvothermal synthesis and crystal structure of the one-dimensional coordination polymer Ni(DMBDIZ) (OOCMe)₂ (DMBDIZ = 2,6-dimethyl-benzo[1,2-d:4,5-d′]diimidazole) are described. Each nickel ion is located in pseudo-octahedral geometry formed by four oxygen atoms from two bidentate acetate anions and two trans-related tertiary nitrogen donors from two different DMBDIZ ligands. The DMBDIZ entity acts as a trans exo-bidentate ligand and bridges the nickel ions to form a uniform linear chain with Ni⋯Ni separation = 8.703 Å. The hydrogen bonding between the acetate anions and the ligands contributes to the enhancement of the structural dimensionality. Variable-temperature magnetic susceptibility measurements (2.0-300 K) reveal the presence of a very weak ferromagnetic interaction between the magnetic centers.

Original language	English
Pages (from-to)	312-315
Number of pages	4
Journal	Transition Metal Chemistry
Volume	28
Issue number	3
DOIs	https://doi.org/10.1023/A:1022996703047
State	Published - Apr 2003
Externally published	Yes

Access to Document

10.1023/A:1022996703047

Cite this

@article{c4444b2d56fa4b9fba8b4cfe9b739960,

title = "Solvothermal synthesis, crystal structure and magnetic properties of the one-dimensional coordination polymer Ni(DMBDIZ)(OOCMe)2 (DMBDIZ = 2,6-dimethylbenzo[1,2-d:4,5-d′]diimidazole)",

abstract = "The solvothermal synthesis and crystal structure of the one-dimensional coordination polymer Ni(DMBDIZ) (OOCMe)2 (DMBDIZ = 2,6-dimethyl-benzo[1,2-d:4,5-d′]diimidazole) are described. Each nickel ion is located in pseudo-octahedral geometry formed by four oxygen atoms from two bidentate acetate anions and two trans-related tertiary nitrogen donors from two different DMBDIZ ligands. The DMBDIZ entity acts as a trans exo-bidentate ligand and bridges the nickel ions to form a uniform linear chain with Ni⋯Ni separation = 8.703 {\AA}. The hydrogen bonding between the acetate anions and the ligands contributes to the enhancement of the structural dimensionality. Variable-temperature magnetic susceptibility measurements (2.0-300 K) reveal the presence of a very weak ferromagnetic interaction between the magnetic centers.",

author = "Cai, {Chen Xin} and Tian, {Yun Qi} and Ren, {Xiao Ming} and Li, {Yi Zhi} and You, {Xiao Zeng}",

year = "2003",

month = apr,

doi = "10.1023/A:1022996703047",

language = "英语",

volume = "28",

pages = "312--315",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "3",

}

Solvothermal synthesis, crystal structure and magnetic properties of the one-dimensional coordination polymer Ni(DMBDIZ)(OOCMe)₂ (DMBDIZ = 2,6-dimethylbenzo[1,2-d:4,5-d′]diimidazole). / Cai, Chen Xin; Tian, Yun Qi; Ren, Xiao Ming et al.
In: Transition Metal Chemistry, Vol. 28, No. 3, 04.2003, p. 312-315.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Solvothermal synthesis, crystal structure and magnetic properties of the one-dimensional coordination polymer Ni(DMBDIZ)(OOCMe)2 (DMBDIZ = 2,6-dimethylbenzo[1,2-d:4,5-d′]diimidazole)

AU - Cai, Chen Xin

AU - Tian, Yun Qi

AU - Ren, Xiao Ming

AU - Li, Yi Zhi

AU - You, Xiao Zeng

PY - 2003/4

Y1 - 2003/4

N2 - The solvothermal synthesis and crystal structure of the one-dimensional coordination polymer Ni(DMBDIZ) (OOCMe)2 (DMBDIZ = 2,6-dimethyl-benzo[1,2-d:4,5-d′]diimidazole) are described. Each nickel ion is located in pseudo-octahedral geometry formed by four oxygen atoms from two bidentate acetate anions and two trans-related tertiary nitrogen donors from two different DMBDIZ ligands. The DMBDIZ entity acts as a trans exo-bidentate ligand and bridges the nickel ions to form a uniform linear chain with Ni⋯Ni separation = 8.703 Å. The hydrogen bonding between the acetate anions and the ligands contributes to the enhancement of the structural dimensionality. Variable-temperature magnetic susceptibility measurements (2.0-300 K) reveal the presence of a very weak ferromagnetic interaction between the magnetic centers.

AB - The solvothermal synthesis and crystal structure of the one-dimensional coordination polymer Ni(DMBDIZ) (OOCMe)2 (DMBDIZ = 2,6-dimethyl-benzo[1,2-d:4,5-d′]diimidazole) are described. Each nickel ion is located in pseudo-octahedral geometry formed by four oxygen atoms from two bidentate acetate anions and two trans-related tertiary nitrogen donors from two different DMBDIZ ligands. The DMBDIZ entity acts as a trans exo-bidentate ligand and bridges the nickel ions to form a uniform linear chain with Ni⋯Ni separation = 8.703 Å. The hydrogen bonding between the acetate anions and the ligands contributes to the enhancement of the structural dimensionality. Variable-temperature magnetic susceptibility measurements (2.0-300 K) reveal the presence of a very weak ferromagnetic interaction between the magnetic centers.

UR - http://www.scopus.com/inward/record.url?scp=0038005431&partnerID=8YFLogxK

U2 - 10.1023/A:1022996703047

DO - 10.1023/A:1022996703047

M3 - 文章

AN - SCOPUS:0038005431

SN - 0340-4285

VL - 28

SP - 312

EP - 315

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 3

ER -

Solvothermal synthesis, crystal structure and magnetic properties of the one-dimensional coordination polymer Ni(DMBDIZ)(OOCMe)₂ (DMBDIZ = 2,6-dimethylbenzo[1,2-d:4,5-d′]diimidazole)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this