Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate

Wanli Zhou; Qi Chen; Ning Jiang; Xiang Meng; Dunru Zhu; Yan Xu

doi:10.1016/j.ica.2009.02.042

Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate

Wanli Zhou, Qi Chen, Ning Jiang, Xiang Meng, Dunru Zhu, Yan Xu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The first organic amine templated 1-D holmium sulfate [C₆N₄H₂₂]_1.5[Ho₂(SO₄)₆ · H₂O] 1 has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA and ICP. The structure of framework compound 1 is constructed from the [-Ho-O-S-O-]_n chains. Two types of [-Ho-O-S-O-]_n chains connect each other by sharing the bridging SO₄^{2 -} groups to generate a Ho-O-S ladder, while the adjacent ladders are connected by μ₃-O atoms to form a novel triple ladders. The fully protonated triethylenetetraamine molecules are situated between the ladders, and involved in the hydrogen bonding with oxygen atoms of inorganic framework.

Original language	English
Pages (from-to)	3299-3302
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	362
Issue number	9
DOIs	https://doi.org/10.1016/j.ica.2009.02.042
State	Published - 1 Jul 2009

Keywords

1-D
Crystal structure
Holmium sulfate
Solvothermal synthesis

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10.1016/j.ica.2009.02.042

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title = "Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate",

abstract = "The first organic amine templated 1-D holmium sulfate [C6N4H22]1.5[Ho2(SO4)6 · H2O] 1 has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA and ICP. The structure of framework compound 1 is constructed from the [-Ho-O-S-O-]n chains. Two types of [-Ho-O-S-O-]n chains connect each other by sharing the bridging SO42 - groups to generate a Ho-O-S ladder, while the adjacent ladders are connected by μ3-O atoms to form a novel triple ladders. The fully protonated triethylenetetraamine molecules are situated between the ladders, and involved in the hydrogen bonding with oxygen atoms of inorganic framework.",

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author = "Wanli Zhou and Qi Chen and Ning Jiang and Xiang Meng and Dunru Zhu and Yan Xu",

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AU - Zhou, Wanli

AU - Chen, Qi

AU - Jiang, Ning

AU - Meng, Xiang

AU - Zhu, Dunru

AU - Xu, Yan

PY - 2009/7/1

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N2 - The first organic amine templated 1-D holmium sulfate [C6N4H22]1.5[Ho2(SO4)6 · H2O] 1 has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA and ICP. The structure of framework compound 1 is constructed from the [-Ho-O-S-O-]n chains. Two types of [-Ho-O-S-O-]n chains connect each other by sharing the bridging SO42 - groups to generate a Ho-O-S ladder, while the adjacent ladders are connected by μ3-O atoms to form a novel triple ladders. The fully protonated triethylenetetraamine molecules are situated between the ladders, and involved in the hydrogen bonding with oxygen atoms of inorganic framework.

AB - The first organic amine templated 1-D holmium sulfate [C6N4H22]1.5[Ho2(SO4)6 · H2O] 1 has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA and ICP. The structure of framework compound 1 is constructed from the [-Ho-O-S-O-]n chains. Two types of [-Ho-O-S-O-]n chains connect each other by sharing the bridging SO42 - groups to generate a Ho-O-S ladder, while the adjacent ladders are connected by μ3-O atoms to form a novel triple ladders. The fully protonated triethylenetetraamine molecules are situated between the ladders, and involved in the hydrogen bonding with oxygen atoms of inorganic framework.

KW - 1-D

KW - Crystal structure

KW - Holmium sulfate

KW - Solvothermal synthesis

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Solvothermal synthesis, crystal structure and properties of a novel 1-D organic amine templated holmium sulfate

Abstract

Keywords

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