Solvothermal synthesis, crystal structure and properties of the first organic-templated holmium sulfate [C2N2H 10]3[Ho2(SO4)6· 2H2O]

Wanli Zhou; Qi Chen; Dunru Zhu; Yan Xu

doi:10.1002/zaac.200801330

Solvothermal synthesis, crystal structure and properties of the first organic-templated holmium sulfate [C₂N₂H ₁₀]₃[Ho₂(SO₄)₆· 2H₂O]

Wanli Zhou, Qi Chen, Dunru Zhu, Yan Xu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The first organic amine-templated holmium sulfate [C₂N ₂H₁₀]₃[Ho₂(SO₄) ₆·2H₂O] (1) has been synthesized solvo-thermally and has been structurally characterized by single-crystal X-ray diffraction studies. IR spectroscopic, thermogravimetric (TG) and inductivity coupled plasma (ICP) measurements. Crystal analyses of compound 1 showed a novel inorganic layer constructed from the zigzag and helical [-Ho-O-S-O-]_n chains, both of the chains are connected by μ-2 SO₄^2- groups to form 10-membered rings. The solvent plays an important role during the formation of 1.

Original language	English
Pages (from-to)	572-576
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	635
Issue number	3
DOIs	https://doi.org/10.1002/zaac.200801330
State	Published - Mar 2009

Keywords

Holmium sulfate
Lanthanides
Organometallic compounds
Solvothermal synthesis
Template synthesis

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10.1002/zaac.200801330

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abstract = "The first organic amine-templated holmium sulfate [C2N 2H10]3[Ho2(SO4) 6·2H2O] (1) has been synthesized solvo-thermally and has been structurally characterized by single-crystal X-ray diffraction studies. IR spectroscopic, thermogravimetric (TG) and inductivity coupled plasma (ICP) measurements. Crystal analyses of compound 1 showed a novel inorganic layer constructed from the zigzag and helical [-Ho-O-S-O-]n chains, both of the chains are connected by μ-2 SO42- groups to form 10-membered rings. The solvent plays an important role during the formation of 1.",

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author = "Wanli Zhou and Qi Chen and Dunru Zhu and Yan Xu",

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AU - Zhu, Dunru

AU - Xu, Yan

PY - 2009/3

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AB - The first organic amine-templated holmium sulfate [C2N 2H10]3[Ho2(SO4) 6·2H2O] (1) has been synthesized solvo-thermally and has been structurally characterized by single-crystal X-ray diffraction studies. IR spectroscopic, thermogravimetric (TG) and inductivity coupled plasma (ICP) measurements. Crystal analyses of compound 1 showed a novel inorganic layer constructed from the zigzag and helical [-Ho-O-S-O-]n chains, both of the chains are connected by μ-2 SO42- groups to form 10-membered rings. The solvent plays an important role during the formation of 1.

KW - Holmium sulfate

KW - Lanthanides

KW - Organometallic compounds

KW - Solvothermal synthesis

KW - Template synthesis

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Solvothermal synthesis, crystal structure and properties of the first organic-templated holmium sulfate [C₂N₂H ₁₀]₃[Ho₂(SO₄)₆· 2H₂O]

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