Spontaneous magnetization in [1-(4-cyanobenzyl)pyridinium][Pt(mnt)2]: Synthesis, crystal structure and magnetic property

Jingli Xie; Xiaoming Ren; You Song; Wenjun Tong; Changsheng Lu; Yuangen Yao; Qingjin Meng

doi:10.1016/S1387-7003(02)00411-2

Spontaneous magnetization in [1-(4-cyanobenzyl)pyridinium][Pt(mnt)₂]: Synthesis, crystal structure and magnetic property

Jingli Xie, Xiaoming Ren, You Song, Wenjun Tong, Changsheng Lu, Yuangen Yao, Qingjin Meng

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A new complex [1-(4-cyanobenzyl)pyridinium][Pt(mnt)₂] (1), in which mnt^2- = maleonitriledithiolate, has been prepared and characterized. In the solid state, anions and cations of 1 form completely segregated stacking column, and the [Pt(mnt)₂]^- anion column behaves as one-dimensional (1-D) spaced magnetic chains. 1 spontaneously magnetizes at low temperature, which may arises from spin canting.

Original language	English
Pages (from-to)	395-398
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	5
Issue number	6
DOIs	https://doi.org/10.1016/S1387-7003(02)00411-2
State	Published - 2002
Externally published	Yes

Keywords

Crystal structure
Magnetic property
Maleonitriledithiolate
Spin canting

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10.1016/S1387-7003(02)00411-2

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title = "Spontaneous magnetization in [1-(4-cyanobenzyl)pyridinium][Pt(mnt)2]: Synthesis, crystal structure and magnetic property",

abstract = "A new complex [1-(4-cyanobenzyl)pyridinium][Pt(mnt)2] (1), in which mnt2- = maleonitriledithiolate, has been prepared and characterized. In the solid state, anions and cations of 1 form completely segregated stacking column, and the [Pt(mnt)2]- anion column behaves as one-dimensional (1-D) spaced magnetic chains. 1 spontaneously magnetizes at low temperature, which may arises from spin canting.",

keywords = "Crystal structure, Magnetic property, Maleonitriledithiolate, Spin canting",

author = "Jingli Xie and Xiaoming Ren and You Song and Wenjun Tong and Changsheng Lu and Yuangen Yao and Qingjin Meng",

year = "2002",

doi = "10.1016/S1387-7003(02)00411-2",

language = "英语",

volume = "5",

pages = "395--398",

journal = "Inorganic Chemistry Communications",

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T1 - Spontaneous magnetization in [1-(4-cyanobenzyl)pyridinium][Pt(mnt)2]

T2 - Synthesis, crystal structure and magnetic property

AU - Xie, Jingli

AU - Ren, Xiaoming

AU - Song, You

AU - Tong, Wenjun

AU - Lu, Changsheng

AU - Yao, Yuangen

AU - Meng, Qingjin

PY - 2002

Y1 - 2002

N2 - A new complex [1-(4-cyanobenzyl)pyridinium][Pt(mnt)2] (1), in which mnt2- = maleonitriledithiolate, has been prepared and characterized. In the solid state, anions and cations of 1 form completely segregated stacking column, and the [Pt(mnt)2]- anion column behaves as one-dimensional (1-D) spaced magnetic chains. 1 spontaneously magnetizes at low temperature, which may arises from spin canting.

AB - A new complex [1-(4-cyanobenzyl)pyridinium][Pt(mnt)2] (1), in which mnt2- = maleonitriledithiolate, has been prepared and characterized. In the solid state, anions and cations of 1 form completely segregated stacking column, and the [Pt(mnt)2]- anion column behaves as one-dimensional (1-D) spaced magnetic chains. 1 spontaneously magnetizes at low temperature, which may arises from spin canting.

KW - Crystal structure

KW - Magnetic property

KW - Maleonitriledithiolate

KW - Spin canting

UR - http://www.scopus.com/inward/record.url?scp=0036285234&partnerID=8YFLogxK

U2 - 10.1016/S1387-7003(02)00411-2

DO - 10.1016/S1387-7003(02)00411-2

M3 - 文章

AN - SCOPUS:0036285234

SN - 1387-7003

VL - 5

SP - 395

EP - 398

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Spontaneous magnetization in [1-(4-cyanobenzyl)pyridinium][Pt(mnt)₂]: Synthesis, crystal structure and magnetic property

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Keywords

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