TY - JOUR
T1 - Studies on two cadmium(II) and two zinc(II) complexes of 4′-chloro-2,2′
T2 - 6′,2″-terpyridine with 1:1 or 1:2 ratio of metal and ligand
AU - You, Wei
AU - Huang, Wei
AU - Fan, Ying
AU - Yao, Cheng
PY - 2009/7
Y1 - 2009/7
N2 - The reaction between 4′-chloro-2,2′:6′,2″-terpyridine (tpyCl) with d 10 transition-metal ions produced two cadmium(II) and two zinc(II) metal complexes, formulated as [Cd(tpyCl-k{cyrillic} 3N,N′,N″)(NO 3-k{cyrillic} 2O,O′)(NO 3-k{cyrillic}O)(H 2O-k{cyrillic}O)] (1), [Cd(tpyCl-k{cyrillic} 3N,N′,N″) 2](ClO 4) 2 (2), [Zn(tpyCl-k{cyrillic} 3N,N′,N″) 2](ClO 4) 2 (3), and [Zn(tpyCl-k{cyrillic} 3N,N′,N″) 2](BF 4) 2 (4). Supramolecular interactions include coordinative bonding, O-H ··· O, O-H ··· Cl, C-H ··· F, and C-H ··· Cl hydrogen bonding and π-π stacking, all of which play essential roles in forming different frameworks of 1-4.
AB - The reaction between 4′-chloro-2,2′:6′,2″-terpyridine (tpyCl) with d 10 transition-metal ions produced two cadmium(II) and two zinc(II) metal complexes, formulated as [Cd(tpyCl-k{cyrillic} 3N,N′,N″)(NO 3-k{cyrillic} 2O,O′)(NO 3-k{cyrillic}O)(H 2O-k{cyrillic}O)] (1), [Cd(tpyCl-k{cyrillic} 3N,N′,N″) 2](ClO 4) 2 (2), [Zn(tpyCl-k{cyrillic} 3N,N′,N″) 2](ClO 4) 2 (3), and [Zn(tpyCl-k{cyrillic} 3N,N′,N″) 2](BF 4) 2 (4). Supramolecular interactions include coordinative bonding, O-H ··· O, O-H ··· Cl, C-H ··· F, and C-H ··· Cl hydrogen bonding and π-π stacking, all of which play essential roles in forming different frameworks of 1-4.
KW - 4′-chloro-2,2′:6′,2′-terpyridine
KW - Crystal structures
KW - Supramolecular interactions
KW - d Transition-metal ion complexes
UR - http://www.scopus.com/inward/record.url?scp=69849084366&partnerID=8YFLogxK
U2 - 10.1080/00958970902780606
DO - 10.1080/00958970902780606
M3 - 文章
AN - SCOPUS:69849084366
SN - 0095-8972
VL - 62
SP - 2125
EP - 2137
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 13
ER -