Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

Wenqin Wang; Li Wang; Xiaochen Dong; Tianxu Sun; Jianfeng Wang

doi:10.1002/app.23721

Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

Wenqin Wang, Li Wang, Xiaochen Dong, Tianxu Sun, Jianfeng Wang

Zhejiang University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by ¹³C NMR. It was found that the different carriers have slight effect on the composite of copolymer.

Original language	English
Pages (from-to)	1574-1577
Number of pages	4
Journal	Journal of Applied Polymer Science
Volume	102
Issue number	2
DOIs	https://doi.org/10.1002/app.23721
State	Published - 15 Oct 2006
Externally published	Yes

Keywords

Copolymerization
Ethylene/1-hexene
Kinetics
Polystyrene-supported metallocene

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10.1002/app.23721

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title = "Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst",

abstract = "Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer.",

keywords = "Copolymerization, Ethylene/1-hexene, Kinetics, Polystyrene-supported metallocene",

author = "Wenqin Wang and Li Wang and Xiaochen Dong and Tianxu Sun and Jianfeng Wang",

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T1 - Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

AU - Wang, Wenqin

AU - Wang, Li

AU - Dong, Xiaochen

AU - Sun, Tianxu

AU - Wang, Jianfeng

PY - 2006/10/15

Y1 - 2006/10/15

N2 - Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer.

AB - Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer.

KW - Copolymerization

KW - Ethylene/1-hexene

KW - Kinetics

KW - Polystyrene-supported metallocene

UR - http://www.scopus.com/inward/record.url?scp=33749583141&partnerID=8YFLogxK

U2 - 10.1002/app.23721

DO - 10.1002/app.23721

M3 - 文章

AN - SCOPUS:33749583141

SN - 0021-8995

VL - 102

SP - 1574

EP - 1577

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 2

ER -

Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

Abstract

Keywords

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