TY - JOUR
T1 - Study on electrosorption of as ions in aqueous solution by modified graphene
AU - Xu, Bin
AU - Wu, Wen Qian
AU - Gao, Hai Ling
AU - Zhang, Yi Min
AU - Zhang, Shu Ling
N1 - Publisher Copyright:
© 2020, China Environmental Science Press. All rights reserved.
PY - 2020/4/25
Y1 - 2020/4/25
N2 - In this paper, the modified graphene material, graphene/titanium dioxide (GA/TiO2) composite, was prepared by hydrothermal method. The morphology, pore structure and electrochemical properties of graphene (GA) and GA/TiO2 were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption, Raman spectroscopy and electrochemistry. Then GA and GA/TiO2 were assembled into electrodes to remove As ions by capacitive deionization (CDI) method. The removal efficiency of As ions was analyzed through different experimental conditions including voltage, circulating flow rate, temperature and initial As ion concentration. The results show that GA/TiO2 had a three-dimensional porous structure with specific surface area of 416.99 m2·g-1 and specific capacitance of 320.75 F·g-1, which were better than that of GA. In addition, the removal performance of As ions by CDI on GA/TiO2 electrode was better than that of GA electrode. The removal efficiency and adsorption capacity of As ions increased with the increase in voltage, but decreased with the increase in temperature. However, the removal efficiency decreased and adsorption capacity increased with the increase in initial ion concentration. The circulating flow rate had no significant effect on the removal efficiency. Moreover, the adsorption process of As ions on GA/TiO2 electrode can be well fitted by the pseudo-first order kinetic model and Freundlich model.
AB - In this paper, the modified graphene material, graphene/titanium dioxide (GA/TiO2) composite, was prepared by hydrothermal method. The morphology, pore structure and electrochemical properties of graphene (GA) and GA/TiO2 were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption, Raman spectroscopy and electrochemistry. Then GA and GA/TiO2 were assembled into electrodes to remove As ions by capacitive deionization (CDI) method. The removal efficiency of As ions was analyzed through different experimental conditions including voltage, circulating flow rate, temperature and initial As ion concentration. The results show that GA/TiO2 had a three-dimensional porous structure with specific surface area of 416.99 m2·g-1 and specific capacitance of 320.75 F·g-1, which were better than that of GA. In addition, the removal performance of As ions by CDI on GA/TiO2 electrode was better than that of GA electrode. The removal efficiency and adsorption capacity of As ions increased with the increase in voltage, but decreased with the increase in temperature. However, the removal efficiency decreased and adsorption capacity increased with the increase in initial ion concentration. The circulating flow rate had no significant effect on the removal efficiency. Moreover, the adsorption process of As ions on GA/TiO2 electrode can be well fitted by the pseudo-first order kinetic model and Freundlich model.
KW - As ions
KW - Capacitance deionization technology
KW - Graphene
KW - Titanium dioxide
UR - http://www.scopus.com/inward/record.url?scp=85088564934&partnerID=8YFLogxK
U2 - 10.19741/j.issn.1673-4831.2019.0863
DO - 10.19741/j.issn.1673-4831.2019.0863
M3 - 文章
AN - SCOPUS:85088564934
SN - 1673-4831
VL - 36
SP - 531
EP - 541
JO - Journal of Ecology and Rural Environment
JF - Journal of Ecology and Rural Environment
IS - 4
M1 - 1673-4831(2020)04-0531-11
ER -