Study on extraction-oxidation desulfurization of model oil by acidic ionic liquid

Cun Zhang; Feng Wang; Xiao Yu Pan; Xiao Qin Liu

doi:10.1016/s1872-5813(11)60041-8

Study on extraction-oxidation desulfurization of model oil by acidic ionic liquid

Cun Zhang, Feng Wang, Xiao Yu Pan, Xiao Qin Liu

College of Chemical Engineering

Yangzhou University

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Acidic ionic liquid N-carboxymethylpyridine hydrosulphate ([CH₂COOHPy]HSO₄) as the extractant and catalyst, and hydrogen peroxide as the oxidant were used to the extraction-oxidation desulphurization of model oil (dibenzothiophene dissolved in n-octane). The effects of the amounts of hydrogen peroxide and ionic liquid, reaction temperature and reaction time on the sulfur removal were investigated. The results show that when molar ratio of sulfur to H₂O₂ is 1:6, volume ratio of ionic liquid to model oil is 0.6:10, and reaction time is 40 min at 50°C, the sulfur removal of model oil can reach 99.7%. The ionic liquid can be recycled 5 times without obvious decrease in the sulfur removal.

Original language	English
Pages (from-to)	689-693
Number of pages	5
Journal	Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology
Volume	39
Issue number	9
DOIs	https://doi.org/10.1016/s1872-5813(11)60041-8
State	Published - Sep 2011

Keywords

Desulfurization
Dibenzothiophene
Extraction-oxidation
Ionic liquid
Model oil

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10.1016/s1872-5813(11)60041-8

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title = "Study on extraction-oxidation desulfurization of model oil by acidic ionic liquid",

abstract = "Acidic ionic liquid N-carboxymethylpyridine hydrosulphate ([CH2COOHPy]HSO4) as the extractant and catalyst, and hydrogen peroxide as the oxidant were used to the extraction-oxidation desulphurization of model oil (dibenzothiophene dissolved in n-octane). The effects of the amounts of hydrogen peroxide and ionic liquid, reaction temperature and reaction time on the sulfur removal were investigated. The results show that when molar ratio of sulfur to H2O2 is 1:6, volume ratio of ionic liquid to model oil is 0.6:10, and reaction time is 40 min at 50°C, the sulfur removal of model oil can reach 99.7%. The ionic liquid can be recycled 5 times without obvious decrease in the sulfur removal.",

keywords = "Desulfurization, Dibenzothiophene, Extraction-oxidation, Ionic liquid, Model oil",

author = "Cun Zhang and Feng Wang and Pan, {Xiao Yu} and Liu, {Xiao Qin}",

year = "2011",

month = sep,

doi = "10.1016/s1872-5813(11)60041-8",

language = "英语",

volume = "39",

pages = "689--693",

journal = "Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology",

issn = "2097-213X",

publisher = "Science China Press",

number = "9",

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TY - JOUR

T1 - Study on extraction-oxidation desulfurization of model oil by acidic ionic liquid

AU - Zhang, Cun

AU - Wang, Feng

AU - Pan, Xiao Yu

AU - Liu, Xiao Qin

PY - 2011/9

Y1 - 2011/9

N2 - Acidic ionic liquid N-carboxymethylpyridine hydrosulphate ([CH2COOHPy]HSO4) as the extractant and catalyst, and hydrogen peroxide as the oxidant were used to the extraction-oxidation desulphurization of model oil (dibenzothiophene dissolved in n-octane). The effects of the amounts of hydrogen peroxide and ionic liquid, reaction temperature and reaction time on the sulfur removal were investigated. The results show that when molar ratio of sulfur to H2O2 is 1:6, volume ratio of ionic liquid to model oil is 0.6:10, and reaction time is 40 min at 50°C, the sulfur removal of model oil can reach 99.7%. The ionic liquid can be recycled 5 times without obvious decrease in the sulfur removal.

AB - Acidic ionic liquid N-carboxymethylpyridine hydrosulphate ([CH2COOHPy]HSO4) as the extractant and catalyst, and hydrogen peroxide as the oxidant were used to the extraction-oxidation desulphurization of model oil (dibenzothiophene dissolved in n-octane). The effects of the amounts of hydrogen peroxide and ionic liquid, reaction temperature and reaction time on the sulfur removal were investigated. The results show that when molar ratio of sulfur to H2O2 is 1:6, volume ratio of ionic liquid to model oil is 0.6:10, and reaction time is 40 min at 50°C, the sulfur removal of model oil can reach 99.7%. The ionic liquid can be recycled 5 times without obvious decrease in the sulfur removal.

KW - Desulfurization

KW - Dibenzothiophene

KW - Extraction-oxidation

KW - Ionic liquid

KW - Model oil

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U2 - 10.1016/s1872-5813(11)60041-8

DO - 10.1016/s1872-5813(11)60041-8

M3 - 文章

AN - SCOPUS:80054683450

SN - 2097-213X

VL - 39

SP - 689

EP - 693

JO - Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology

JF - Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology

IS - 9

ER -

Study on extraction-oxidation desulfurization of model oil by acidic ionic liquid

Abstract

Keywords

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