Study on the one-step synthesis of tetraallylsilane

Hongfei Gao; Xiangqian Guo; Gang Yang; Nanping Xu

Study on the one-step synthesis of tetraallylsilane

Hongfei Gao, Xiangqian Guo, Gang Yang, Nanping Xu

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

Abstract

Tetraallylsilane was synthesized by one-step approach through the reaction of silicon tetrachloride with the partially solvated Grignard reagents formed in situ from allyl bromide and magnesium in the mixed solvents of toluene and ether. The yield was 91% when the molar ratio of diethyl ether and allyl bromide was 4 (meanwhile, V_toluene/V_ether = 1.1). The yield was also around 63% when using THF instead of diethyl ether (V_toluene/ V_THF = 1-7). This one-step approach proved promising for the industrial production due to the high yield and the low cost.

Original language	English
Pages (from-to)	705-707
Number of pages	3
Journal	Chemistry Bulletin / Huaxue Tongbao
Volume	69
Issue number	9
State	Published - 2006

Keywords

Grignard reaction
One-step approach
Tetraallylsilane

Cite this

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title = "Study on the one-step synthesis of tetraallylsilane",

abstract = "Tetraallylsilane was synthesized by one-step approach through the reaction of silicon tetrachloride with the partially solvated Grignard reagents formed in situ from allyl bromide and magnesium in the mixed solvents of toluene and ether. The yield was 91% when the molar ratio of diethyl ether and allyl bromide was 4 (meanwhile, Vtoluene/Vether = 1.1). The yield was also around 63% when using THF instead of diethyl ether (Vtoluene/ VTHF = 1-7). This one-step approach proved promising for the industrial production due to the high yield and the low cost.",

keywords = "Grignard reaction, One-step approach, Tetraallylsilane",

author = "Hongfei Gao and Xiangqian Guo and Gang Yang and Nanping Xu",

year = "2006",

language = "英语",

volume = "69",

pages = "705--707",

journal = "Chemistry Bulletin / Huaxue Tongbao",

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TY - JOUR

T1 - Study on the one-step synthesis of tetraallylsilane

AU - Gao, Hongfei

AU - Guo, Xiangqian

AU - Yang, Gang

AU - Xu, Nanping

PY - 2006

Y1 - 2006

N2 - Tetraallylsilane was synthesized by one-step approach through the reaction of silicon tetrachloride with the partially solvated Grignard reagents formed in situ from allyl bromide and magnesium in the mixed solvents of toluene and ether. The yield was 91% when the molar ratio of diethyl ether and allyl bromide was 4 (meanwhile, Vtoluene/Vether = 1.1). The yield was also around 63% when using THF instead of diethyl ether (Vtoluene/ VTHF = 1-7). This one-step approach proved promising for the industrial production due to the high yield and the low cost.

AB - Tetraallylsilane was synthesized by one-step approach through the reaction of silicon tetrachloride with the partially solvated Grignard reagents formed in situ from allyl bromide and magnesium in the mixed solvents of toluene and ether. The yield was 91% when the molar ratio of diethyl ether and allyl bromide was 4 (meanwhile, Vtoluene/Vether = 1.1). The yield was also around 63% when using THF instead of diethyl ether (Vtoluene/ VTHF = 1-7). This one-step approach proved promising for the industrial production due to the high yield and the low cost.

KW - Grignard reaction

KW - One-step approach

KW - Tetraallylsilane

UR - http://www.scopus.com/inward/record.url?scp=33947176554&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:33947176554

SN - 0441-3776

VL - 69

SP - 705

EP - 707

JO - Chemistry Bulletin / Huaxue Tongbao

JF - Chemistry Bulletin / Huaxue Tongbao

IS - 9

ER -

Study on the one-step synthesis of tetraallylsilane

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