TY - JOUR
T1 - Syntheses and crystal structures of two copper complexes with pyridyl-substituted phenol ligand
AU - Gao, Da Zhi
AU - Wang, Ruo Xu
AU - Ye, Fan
AU - Shen, Xuan
AU - Xu, Yan
AU - Zhu, Dun Ru
PY - 2013/11
Y1 - 2013/11
N2 - Two mononuclear copper(II) complexes, [CuL(CH3CN)(ClO4)]ClO4(1) and cis-[CuL(NCS)2]·0.5C4H8O2(2) (L=2-[N,N-di (2-pyridylmethyl)aminomethyl]-6-aldehydo-4-methylphenol) have been synthesized and characterized by UV-Vis, FTIR, ESI-MS, elemental analysis and single crystal X-ray crystallography. Both 1 and 2 crystallize in a monoclinic system. Each copper(II) ion locates in a distorted octahedron geometry. As a tetradentate chelating ligand, the L coordinates to copper(II) ion via two pyridyl N atoms, one N atom of tertiary amine, and one phenol O atom. In 1, an acetonitrile molecule and a perchlorate anion also take part in coordination; while there are two cis-disposed NCS- ions in 2. CCDC: 938954, 1; 938955, 2.
AB - Two mononuclear copper(II) complexes, [CuL(CH3CN)(ClO4)]ClO4(1) and cis-[CuL(NCS)2]·0.5C4H8O2(2) (L=2-[N,N-di (2-pyridylmethyl)aminomethyl]-6-aldehydo-4-methylphenol) have been synthesized and characterized by UV-Vis, FTIR, ESI-MS, elemental analysis and single crystal X-ray crystallography. Both 1 and 2 crystallize in a monoclinic system. Each copper(II) ion locates in a distorted octahedron geometry. As a tetradentate chelating ligand, the L coordinates to copper(II) ion via two pyridyl N atoms, one N atom of tertiary amine, and one phenol O atom. In 1, an acetonitrile molecule and a perchlorate anion also take part in coordination; while there are two cis-disposed NCS- ions in 2. CCDC: 938954, 1; 938955, 2.
KW - Crystal structure
KW - Cu(II) complex
KW - Phenol ligand
UR - http://www.scopus.com/inward/record.url?scp=84907010687&partnerID=8YFLogxK
U2 - 10.3969/j.issn.1001-4861.2013.00.384
DO - 10.3969/j.issn.1001-4861.2013.00.384
M3 - 文章
AN - SCOPUS:84907010687
SN - 1001-4861
VL - 29
SP - 2438
EP - 2444
JO - Chinese Journal of Inorganic Chemistry
JF - Chinese Journal of Inorganic Chemistry
IS - 11
ER -