Syntheses and crystal structures of two one-dimensional 3d-4f heterobimetallic complexes based on [Fe(bpca)(CN)3]-

Cai Feng Wang; Wei Liu; Yi Zhi Li; Jing Lin Zuo; Xiao Zeng You

Syntheses and crystal structures of two one-dimensional 3d-4f heterobimetallic complexes based on [Fe(bpca)(CN)₃]^-

Cai Feng Wang, Wei Liu, Yi Zhi Li, Jing Lin Zuo, Xiao Zeng You

Nanjing University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Two 3d-4f bimetallic complexes, {[(bpca)Fe (CN)₃Pr (H ₂O)₅]Cl₂}_n (1) and {[(bpca) ₂Fe₂ (CN)₆Pr (H₂O)₆]Cl · 4H₂O}_n (2) (bpca=bis(2-pyridylcarbonyl)amidate anion), have been synthesized and their crystal structures were determined. Complex 1 crystallizes in the orthorhombic space group Pnma while complex 2 is in the triclinic space group P1̄. Both complexes possess novel one-dimensional (1D) chain structures with alternating arrays of [(bpca)Fe (CN₃]^- and [Pr(H₂O)_x]³⁺ (x=5 for 1 and 6 for 2) fragments. They exhibit 3D supramolecular architectures through π-π stacking interactions, hydrogen bonds and short-distance intermolecular interactions. CCDC: 624698,1; 624699, 2.

Original language	English
Pages (from-to)	1017-1022
Number of pages	6
Journal	Chinese Journal of Inorganic Chemistry
Volume	24
Issue number	7
State	Published - Jul 2008
Externally published	Yes

Keywords

3d-4f bimetallic complexes
Chain complexes
Crystal structures
Cyanide bridged

Cite this

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title = "Syntheses and crystal structures of two one-dimensional 3d-4f heterobimetallic complexes based on [Fe(bpca)(CN)3]-",

abstract = "Two 3d-4f bimetallic complexes, {[(bpca)Fe (CN)3Pr (H 2O)5]Cl2}n (1) and {[(bpca) 2Fe2 (CN)6Pr (H2O)6]Cl · 4H2O}n (2) (bpca=bis(2-pyridylcarbonyl)amidate anion), have been synthesized and their crystal structures were determined. Complex 1 crystallizes in the orthorhombic space group Pnma while complex 2 is in the triclinic space group P{\=1}. Both complexes possess novel one-dimensional (1D) chain structures with alternating arrays of [(bpca)Fe (CN3]- and [Pr(H2O)x]3+ (x=5 for 1 and 6 for 2) fragments. They exhibit 3D supramolecular architectures through π-π stacking interactions, hydrogen bonds and short-distance intermolecular interactions. CCDC: 624698,1; 624699, 2.",

keywords = "3d-4f bimetallic complexes, Chain complexes, Crystal structures, Cyanide bridged",

author = "Wang, {Cai Feng} and Wei Liu and Li, {Yi Zhi} and Zuo, {Jing Lin} and You, {Xiao Zeng}",

year = "2008",

month = jul,

language = "英语",

volume = "24",

pages = "1017--1022",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "7",

}

TY - JOUR

T1 - Syntheses and crystal structures of two one-dimensional 3d-4f heterobimetallic complexes based on [Fe(bpca)(CN)3]-

AU - Wang, Cai Feng

AU - Liu, Wei

AU - Li, Yi Zhi

AU - Zuo, Jing Lin

AU - You, Xiao Zeng

PY - 2008/7

Y1 - 2008/7

N2 - Two 3d-4f bimetallic complexes, {[(bpca)Fe (CN)3Pr (H 2O)5]Cl2}n (1) and {[(bpca) 2Fe2 (CN)6Pr (H2O)6]Cl · 4H2O}n (2) (bpca=bis(2-pyridylcarbonyl)amidate anion), have been synthesized and their crystal structures were determined. Complex 1 crystallizes in the orthorhombic space group Pnma while complex 2 is in the triclinic space group P1̄. Both complexes possess novel one-dimensional (1D) chain structures with alternating arrays of [(bpca)Fe (CN3]- and [Pr(H2O)x]3+ (x=5 for 1 and 6 for 2) fragments. They exhibit 3D supramolecular architectures through π-π stacking interactions, hydrogen bonds and short-distance intermolecular interactions. CCDC: 624698,1; 624699, 2.

AB - Two 3d-4f bimetallic complexes, {[(bpca)Fe (CN)3Pr (H 2O)5]Cl2}n (1) and {[(bpca) 2Fe2 (CN)6Pr (H2O)6]Cl · 4H2O}n (2) (bpca=bis(2-pyridylcarbonyl)amidate anion), have been synthesized and their crystal structures were determined. Complex 1 crystallizes in the orthorhombic space group Pnma while complex 2 is in the triclinic space group P1̄. Both complexes possess novel one-dimensional (1D) chain structures with alternating arrays of [(bpca)Fe (CN3]- and [Pr(H2O)x]3+ (x=5 for 1 and 6 for 2) fragments. They exhibit 3D supramolecular architectures through π-π stacking interactions, hydrogen bonds and short-distance intermolecular interactions. CCDC: 624698,1; 624699, 2.

KW - 3d-4f bimetallic complexes

KW - Chain complexes

KW - Crystal structures

KW - Cyanide bridged

UR - http://www.scopus.com/inward/record.url?scp=48249104726&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:48249104726

SN - 1001-4861

VL - 24

SP - 1017

EP - 1022

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 7

ER -

Syntheses and crystal structures of two one-dimensional 3d-4f heterobimetallic complexes based on [Fe(bpca)(CN)₃]^-

Abstract

Keywords

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