Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers

Guang Xiang Liu; Hong Zhou; Xiao Chun Zha; Chun You Zhang; Yan Wang; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1016/j.ica.2012.02.010

Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers

Guang Xiang Liu, Hong Zhou, Xiao Chun Zha, Chun You Zhang, Yan Wang, Sadafumi Nishihara, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Two novel heterometallic coordination polymers, [AgSm(pydc) ₂]·2H ₂O (1) and [AgTb(pydc) ₂] ₂·H ₂O (2) (H ₂pydc = pyridine-3,4- dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complexes 1 and 2 are isomorphous and exhibit 3D open framework heterometallic coordination polymer containing 1D channels occupied by lattice water molecules. To our knowledge, both compounds represent the rare examples of 3D open-framework 4d-4f heterometallic coordination polymers with open framework structure. Moreover, their luminescent and magnetic properties have also been investigated.

Original language	English
Pages (from-to)	308-313
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	387
DOIs	https://doi.org/10.1016/j.ica.2012.02.010
State	Published - 30 May 2012

Keywords

Crystal structure
Heterometallic coordination polymer
Luminescence
Magnetism
Pyridine-3,4-dicarboxylic acid

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10.1016/j.ica.2012.02.010

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title = "Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers",

abstract = "Two novel heterometallic coordination polymers, [AgSm(pydc) 2]·2H 2O (1) and [AgTb(pydc) 2] 2·H 2O (2) (H 2pydc = pyridine-3,4- dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complexes 1 and 2 are isomorphous and exhibit 3D open framework heterometallic coordination polymer containing 1D channels occupied by lattice water molecules. To our knowledge, both compounds represent the rare examples of 3D open-framework 4d-4f heterometallic coordination polymers with open framework structure. Moreover, their luminescent and magnetic properties have also been investigated.",

keywords = "Crystal structure, Heterometallic coordination polymer, Luminescence, Magnetism, Pyridine-3,4-dicarboxylic acid",

author = "Liu, {Guang Xiang} and Hong Zhou and Zha, {Xiao Chun} and Zhang, {Chun You} and Yan Wang and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2012",

month = may,

day = "30",

doi = "10.1016/j.ica.2012.02.010",

language = "英语",

volume = "387",

pages = "308--313",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

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TY - JOUR

T1 - Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers

AU - Liu, Guang Xiang

AU - Zhou, Hong

AU - Zha, Xiao Chun

AU - Zhang, Chun You

AU - Wang, Yan

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2012/5/30

Y1 - 2012/5/30

N2 - Two novel heterometallic coordination polymers, [AgSm(pydc) 2]·2H 2O (1) and [AgTb(pydc) 2] 2·H 2O (2) (H 2pydc = pyridine-3,4- dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complexes 1 and 2 are isomorphous and exhibit 3D open framework heterometallic coordination polymer containing 1D channels occupied by lattice water molecules. To our knowledge, both compounds represent the rare examples of 3D open-framework 4d-4f heterometallic coordination polymers with open framework structure. Moreover, their luminescent and magnetic properties have also been investigated.

AB - Two novel heterometallic coordination polymers, [AgSm(pydc) 2]·2H 2O (1) and [AgTb(pydc) 2] 2·H 2O (2) (H 2pydc = pyridine-3,4- dicarboxylic acid), have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complexes 1 and 2 are isomorphous and exhibit 3D open framework heterometallic coordination polymer containing 1D channels occupied by lattice water molecules. To our knowledge, both compounds represent the rare examples of 3D open-framework 4d-4f heterometallic coordination polymers with open framework structure. Moreover, their luminescent and magnetic properties have also been investigated.

KW - Crystal structure

KW - Heterometallic coordination polymer

KW - Luminescence

KW - Magnetism

KW - Pyridine-3,4-dicarboxylic acid

UR - http://www.scopus.com/inward/record.url?scp=84862828380&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2012.02.010

DO - 10.1016/j.ica.2012.02.010

M3 - 文章

AN - SCOPUS:84862828380

SN - 0020-1693

VL - 387

SP - 308

EP - 313

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Syntheses, crystal structures and physical properties of two unusual 4d-4f heterometallic coordination polymers

Abstract

Keywords

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