Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

Guang Xiang Liu; Kun Zhu; Sadafumi Nishihara; Rong Yi Huang; Xiao Ming Ren

doi:10.1016/j.ica.2009.09.014

Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

Guang Xiang Liu, Kun Zhu, Sadafumi Nishihara, Rong Yi Huang, Xiao Ming Ren

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Hydrothermal reaction of Zn(NO₃)₂·6H₂O with benzene-1,2,3-tricarboxylic acid (H₃BTC) or 5-bromoisophthalic acid (H₂BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn₂(OH)(BTC) (bix)]·H₂O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (4²·6)(4²·6³·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.

Original language	English
Pages (from-to)	5103-5108
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	362
Issue number	14
DOIs	https://doi.org/10.1016/j.ica.2009.09.014
State	Published - 10 Nov 2009
Externally published	Yes

Keywords

Coordination polymer
Luminescence
Polycarboxylate
Zinc

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title = "Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene",

abstract = "Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn2(OH)(BTC) (bix)]·H2O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (42·6)(42·63·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.",

keywords = "Coordination polymer, Luminescence, Polycarboxylate, Zinc",

author = "Liu, {Guang Xiang} and Kun Zhu and Sadafumi Nishihara and Huang, {Rong Yi} and Ren, {Xiao Ming}",

year = "2009",

month = nov,

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doi = "10.1016/j.ica.2009.09.014",

language = "英语",

volume = "362",

pages = "5103--5108",

journal = "Inorganica Chimica Acta",

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T1 - Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

AU - Liu, Guang Xiang

AU - Zhu, Kun

AU - Nishihara, Sadafumi

AU - Huang, Rong Yi

AU - Ren, Xiao Ming

PY - 2009/11/10

Y1 - 2009/11/10

N2 - Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn2(OH)(BTC) (bix)]·H2O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (42·6)(42·63·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.

AB - Hydrothermal reaction of Zn(NO3)2·6H2O with benzene-1,2,3-tricarboxylic acid (H3BTC) or 5-bromoisophthalic acid (H2BIPA) in the presence of 1,4-bis(imidazol-1-ylmethyl)benzene (bix) produced two novel coordination polymers [Zn2(OH)(BTC) (bix)]·H2O (1) and Zn(BIPA)(bix) (2), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR and thermoanalysis. Complex 1 is a novel example of the 2D (3,4)-connected nets with (42·6)(42·63·8) topology. In 2, the BIPA and bix ligands linked the Zn(II) atoms into a deeply corrugated 2D sheet. The corrugated 2D sheets polycatenate each other in a parallel manner yielding a rare 2D → 3D parallel polycatenation net. Thermal and luminescent properties of two complexes have also been investigated.

KW - Coordination polymer

KW - Luminescence

KW - Polycarboxylate

KW - Zinc

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DO - 10.1016/j.ica.2009.09.014

M3 - 文章

AN - SCOPUS:70350029603

SN - 0020-1693

VL - 362

SP - 5103

EP - 5108

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 14

ER -

Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on aromatic polycarboxylate and 1,4-bis(imidazol-1-ylmethyl)benzene

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