Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups

Feng Shi; Hong Yang Li; Xiao Jun Peng; Rong Zhang; Xiao Qiang Chen; Jiang Li Fan; Jing Nan Cui; Björn Åkermark; Li Cheng Sun

Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups

Feng Shi, Hong Yang Li, Xiao Jun Peng, Rong Zhang, Xiao Qiang Chen, Jiang Li Fan, Jing Nan Cui, Björn Åkermark, Li Cheng Sun

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel high valent complexes [M₂(III, III)L(μ-OAc) ₂]·PF₆ (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn₂(II, II)(bpmp) (μ-OAc)₂]-ClO₄ (10). These improvements decreased the difference between the new model and (Mn)₄ cluster (OEC in nature).

Original language	English
Pages (from-to)	89-92
Number of pages	4
Journal	Chinese Chemical Letters
Volume	16
Issue number	1
State	Published - Jan 2005

Keywords

Artificial photosynthesis
Dinuclear complex
OEC

Cite this

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title = "Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups",

abstract = "Two novel high valent complexes [M2(III, III)L(μ-OAc) 2]·PF6 (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(II, II)(bpmp) (μ-OAc)2]-ClO4 (10). These improvements decreased the difference between the new model and (Mn)4 cluster (OEC in nature).",

keywords = "Artificial photosynthesis, Dinuclear complex, OEC",

author = "Feng Shi and Li, {Hong Yang} and Peng, {Xiao Jun} and Rong Zhang and Chen, {Xiao Qiang} and Fan, {Jiang Li} and Cui, {Jing Nan} and Bj{\"o}rn {\AA}kermark and Sun, {Li Cheng}",

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T1 - Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups

AU - Shi, Feng

AU - Li, Hong Yang

AU - Peng, Xiao Jun

AU - Zhang, Rong

AU - Chen, Xiao Qiang

AU - Fan, Jiang Li

AU - Cui, Jing Nan

AU - Åkermark, Björn

AU - Sun, Li Cheng

PY - 2005/1

Y1 - 2005/1

N2 - Two novel high valent complexes [M2(III, III)L(μ-OAc) 2]·PF6 (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(II, II)(bpmp) (μ-OAc)2]-ClO4 (10). These improvements decreased the difference between the new model and (Mn)4 cluster (OEC in nature).

AB - Two novel high valent complexes [M2(III, III)L(μ-OAc) 2]·PF6 (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(II, II)(bpmp) (μ-OAc)2]-ClO4 (10). These improvements decreased the difference between the new model and (Mn)4 cluster (OEC in nature).

KW - Artificial photosynthesis

KW - Dinuclear complex

KW - OEC

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M3 - 文章

AN - SCOPUS:33745019365

SN - 1001-8417

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SP - 89

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JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 1

ER -

Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups

Abstract

Keywords

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