TY - JOUR
T1 - Synthesis and crystal structure of bis{[4-bromo-2,6-bis(N,N- diethylaminomethylene) pyridyl]chloropalladium(II)} tetrachloropalladate(II)
AU - Gao, Hong Fei
AU - Zhu, Dun Ru
AU - Yang, Gang
AU - Xu, Nan Ping
PY - 2006/12
Y1 - 2006/12
N2 - A palladium(II) complex, [PdLCl]2·[PdCl4], [L=4-bromo-2,6-bis(N,N-diethylaminomethylene)pyridine], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group Cc, a=0.845 1(17) nm, b=1.8365(4) nm, c=2.715 8(5) nm, β=93.99(3)°, V=4.2048(15) nm3, Z=4, R1 =0.037 7 and wR2=0.076 9. The coordination geometry of the Pd atom in the cation is a slightly distorted square planar, with one pyridyl N and two N atoms of the diethylamine ligand, together with one Cl atom. The dihedral angle between the square planar (N3PdCl) and the pyridyl ring is 10.3(4)°. CCDC: 623421.
AB - A palladium(II) complex, [PdLCl]2·[PdCl4], [L=4-bromo-2,6-bis(N,N-diethylaminomethylene)pyridine], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group Cc, a=0.845 1(17) nm, b=1.8365(4) nm, c=2.715 8(5) nm, β=93.99(3)°, V=4.2048(15) nm3, Z=4, R1 =0.037 7 and wR2=0.076 9. The coordination geometry of the Pd atom in the cation is a slightly distorted square planar, with one pyridyl N and two N atoms of the diethylamine ligand, together with one Cl atom. The dihedral angle between the square planar (N3PdCl) and the pyridyl ring is 10.3(4)°. CCDC: 623421.
KW - Crystal structure
KW - Palladium(II) complex
KW - Tridentate ligand
UR - http://www.scopus.com/inward/record.url?scp=33845752487&partnerID=8YFLogxK
M3 - 文章
AN - SCOPUS:33845752487
SN - 1001-4861
VL - 22
SP - 2269
EP - 2272
JO - Chinese Journal of Inorganic Chemistry
JF - Chinese Journal of Inorganic Chemistry
IS - 12
ER -