Synthesis and electronic structure of a ferroborirene

Holger Braunschweig; Israel Fernández; Gernot Frenking; Krzysztof Radacki; Fabian Seeler

doi:10.1002/anie.200700382

Synthesis and electronic structure of a ferroborirene

Holger Braunschweig, Israel Fernández, Gernot Frenking, Krzysztof Radacki, Fabian Seeler

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

(Chemical Equation Presented) The photochemically induced transfer of a ferroborylene yielded the first metal-bound borirene (see scheme and product structure, in which the methyl substituents are omitted). Experimental and theoretical data suggest significant it derealization in the three-membered BC₂ ring.

Original language	English
Pages (from-to)	5215-5218
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	27
DOIs	https://doi.org/10.1002/anie.200700382
State	Published - 2007
Externally published	Yes

Keywords

Borirenes
Boron
Boryl complexes
Borylene complexes
Density functional calculations

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10.1002/anie.200700382

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title = "Synthesis and electronic structure of a ferroborirene",

abstract = "(Chemical Equation Presented) The photochemically induced transfer of a ferroborylene yielded the first metal-bound borirene (see scheme and product structure, in which the methyl substituents are omitted). Experimental and theoretical data suggest significant it derealization in the three-membered BC2 ring.",

keywords = "Borirenes, Boron, Boryl complexes, Borylene complexes, Density functional calculations",

author = "Holger Braunschweig and Israel Fern{\'a}ndez and Gernot Frenking and Krzysztof Radacki and Fabian Seeler",

year = "2007",

doi = "10.1002/anie.200700382",

language = "英语",

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T1 - Synthesis and electronic structure of a ferroborirene

AU - Braunschweig, Holger

AU - Fernández, Israel

AU - Frenking, Gernot

AU - Radacki, Krzysztof

AU - Seeler, Fabian

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) The photochemically induced transfer of a ferroborylene yielded the first metal-bound borirene (see scheme and product structure, in which the methyl substituents are omitted). Experimental and theoretical data suggest significant it derealization in the three-membered BC2 ring.

AB - (Chemical Equation Presented) The photochemically induced transfer of a ferroborylene yielded the first metal-bound borirene (see scheme and product structure, in which the methyl substituents are omitted). Experimental and theoretical data suggest significant it derealization in the three-membered BC2 ring.

KW - Borirenes

KW - Boron

KW - Boryl complexes

KW - Borylene complexes

KW - Density functional calculations

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DO - 10.1002/anie.200700382

M3 - 文章

AN - SCOPUS:34447317860

SN - 1433-7851

VL - 46

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 27

ER -

Synthesis and electronic structure of a ferroborirene

Abstract

Keywords

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