Synthesis and fluorescence properties of doping complexes Sm1-xMx (TTA)3 phen as light conversion agent

Jian Li; Ya Ru Ni; Yan Zhang; Chun Hua Lu; Jun Kai Xue; Zhong Zi Xu

Synthesis and fluorescence properties of doping complexes Sm_1-xM_x (TTA)₃ phen as light conversion agent

Jian Li, Ya Ru Ni, Yan Zhang, Chun Hua Lu, Jun Kai Xue, Zhong Zi Xu

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A series of doping complexes Sm_1-xM_x (TTA)₃ phen (M denotes Gd³⁺ or Y³⁺, TTA stands for 2-thenoyltrifluoroacetone, phen denotes 1, 10-phenanthroline, x is the mole fraction of doping elements) as light conversion agent are synthesized by chemical precipitation method, and the characteristics of the compounds are performed using infra-red spectrum (IR), UV-visible absorption and fluorescence spectroscopy. The results indicate that the structure of Sm_1-xM_x (TTA)₃ phen are similar to Sm (TTA)₃ phen, and the characteristic UV absorption peaks of Sm_1-xM_x (TTA)₃phen are depended on organic ligands. Photoluminescence measurements indicate that the complexes emit strong luminescence, which is determined by the transitions of center samarium ion under UV radiation. The strongest luminescence of Sm_0.5Y_0.5 (TTA)₃ phen is at 647 nm, up to 9.5 × 10⁶ cps. The luminescence of Sm_1-xM_x (TTA)₃ was enhanced with the addition of sensitized elements, Y³⁺ is better than Gd³⁺.

Original language	English
Pages (from-to)	2348-2352
Number of pages	5
Journal	Guangzi Xuebao/Acta Photonica Sinica
Volume	38
Issue number	9
State	Published - Sep 2009

Keywords

Fluorescence
Light conversion agent
Samarium
Sensitize ions
Spectroscopy

Cite this

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title = "Synthesis and fluorescence properties of doping complexes Sm1-xMx (TTA)3 phen as light conversion agent",

abstract = "A series of doping complexes Sm1-xMx (TTA)3 phen (M denotes Gd3+ or Y3+, TTA stands for 2-thenoyltrifluoroacetone, phen denotes 1, 10-phenanthroline, x is the mole fraction of doping elements) as light conversion agent are synthesized by chemical precipitation method, and the characteristics of the compounds are performed using infra-red spectrum (IR), UV-visible absorption and fluorescence spectroscopy. The results indicate that the structure of Sm1-xMx (TTA)3 phen are similar to Sm (TTA)3 phen, and the characteristic UV absorption peaks of Sm1-xMx (TTA)3phen are depended on organic ligands. Photoluminescence measurements indicate that the complexes emit strong luminescence, which is determined by the transitions of center samarium ion under UV radiation. The strongest luminescence of Sm0.5Y0.5 (TTA)3 phen is at 647 nm, up to 9.5 × 106 cps. The luminescence of Sm1-xMx (TTA)3 was enhanced with the addition of sensitized elements, Y3+ is better than Gd3+.",

keywords = "Fluorescence, Light conversion agent, Samarium, Sensitize ions, Spectroscopy",

author = "Jian Li and Ni, {Ya Ru} and Yan Zhang and Lu, {Chun Hua} and Xue, {Jun Kai} and Xu, {Zhong Zi}",

year = "2009",

month = sep,

language = "英语",

volume = "38",

pages = "2348--2352",

journal = "Guangzi Xuebao/Acta Photonica Sinica",

issn = "1004-4213",

publisher = "Chinese Optical Society",

number = "9",

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TY - JOUR

T1 - Synthesis and fluorescence properties of doping complexes Sm1-xMx (TTA)3 phen as light conversion agent

AU - Li, Jian

AU - Ni, Ya Ru

AU - Zhang, Yan

AU - Lu, Chun Hua

AU - Xue, Jun Kai

AU - Xu, Zhong Zi

PY - 2009/9

Y1 - 2009/9

N2 - A series of doping complexes Sm1-xMx (TTA)3 phen (M denotes Gd3+ or Y3+, TTA stands for 2-thenoyltrifluoroacetone, phen denotes 1, 10-phenanthroline, x is the mole fraction of doping elements) as light conversion agent are synthesized by chemical precipitation method, and the characteristics of the compounds are performed using infra-red spectrum (IR), UV-visible absorption and fluorescence spectroscopy. The results indicate that the structure of Sm1-xMx (TTA)3 phen are similar to Sm (TTA)3 phen, and the characteristic UV absorption peaks of Sm1-xMx (TTA)3phen are depended on organic ligands. Photoluminescence measurements indicate that the complexes emit strong luminescence, which is determined by the transitions of center samarium ion under UV radiation. The strongest luminescence of Sm0.5Y0.5 (TTA)3 phen is at 647 nm, up to 9.5 × 106 cps. The luminescence of Sm1-xMx (TTA)3 was enhanced with the addition of sensitized elements, Y3+ is better than Gd3+.

AB - A series of doping complexes Sm1-xMx (TTA)3 phen (M denotes Gd3+ or Y3+, TTA stands for 2-thenoyltrifluoroacetone, phen denotes 1, 10-phenanthroline, x is the mole fraction of doping elements) as light conversion agent are synthesized by chemical precipitation method, and the characteristics of the compounds are performed using infra-red spectrum (IR), UV-visible absorption and fluorescence spectroscopy. The results indicate that the structure of Sm1-xMx (TTA)3 phen are similar to Sm (TTA)3 phen, and the characteristic UV absorption peaks of Sm1-xMx (TTA)3phen are depended on organic ligands. Photoluminescence measurements indicate that the complexes emit strong luminescence, which is determined by the transitions of center samarium ion under UV radiation. The strongest luminescence of Sm0.5Y0.5 (TTA)3 phen is at 647 nm, up to 9.5 × 106 cps. The luminescence of Sm1-xMx (TTA)3 was enhanced with the addition of sensitized elements, Y3+ is better than Gd3+.

KW - Fluorescence

KW - Light conversion agent

KW - Samarium

KW - Sensitize ions

KW - Spectroscopy

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M3 - 文章

AN - SCOPUS:70350550333

SN - 1004-4213

VL - 38

SP - 2348

EP - 2352

JO - Guangzi Xuebao/Acta Photonica Sinica

JF - Guangzi Xuebao/Acta Photonica Sinica

IS - 9

ER -

Synthesis and fluorescence properties of doping complexes Sm_1-xM_x (TTA)₃ phen as light conversion agent

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Keywords

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