TY - JOUR
T1 - Synthesis and Properties of High Nitrogen-Oxygen Compounds Based on 5,5″-Azotetrazolate by Using Microreactors
AU - Deng, Qiulin
AU - Du, Jinyan
AU - Lei, Qin
AU - He, Renxiong
AU - Liang, Jianhao
AU - Li, Changlin
AU - Zhang, Lixiong
AU - Jiang, Jinlong
N1 - Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2018/11
Y1 - 2018/11
N2 - A microflow system is easily assembled from a simple T-micromixer, tube microreactor, and several pumps. Herein, the influence of reaction parameters on the microreactor are discussed. The structures of compounds based on 5,5′-azotetrazolate were characterized by FTIR, 1H NMR, and 13C NMR spectroscopy and elemental analysis. The thermal stabilities of these compounds were investigated by differential scanning calorimetry and thermogravimetric analysis, and the heats of formation and densities were estimated by using the Gaussian 09 program for the Born-Haber energy cycle and Monte-Carlo method, respectively. The detonation pressures and detonation velocities of the anhydrous salts were estimated from the Kamlet-Jacobs equation.
AB - A microflow system is easily assembled from a simple T-micromixer, tube microreactor, and several pumps. Herein, the influence of reaction parameters on the microreactor are discussed. The structures of compounds based on 5,5′-azotetrazolate were characterized by FTIR, 1H NMR, and 13C NMR spectroscopy and elemental analysis. The thermal stabilities of these compounds were investigated by differential scanning calorimetry and thermogravimetric analysis, and the heats of formation and densities were estimated by using the Gaussian 09 program for the Born-Haber energy cycle and Monte-Carlo method, respectively. The detonation pressures and detonation velocities of the anhydrous salts were estimated from the Kamlet-Jacobs equation.
KW - Energetic properties
KW - Microreactors
KW - Oxygen-containing salts
UR - http://www.scopus.com/inward/record.url?scp=85054703193&partnerID=8YFLogxK
U2 - 10.1002/ceat.201700694
DO - 10.1002/ceat.201700694
M3 - 文章
AN - SCOPUS:85054703193
SN - 0930-7516
VL - 41
SP - 2274
EP - 2281
JO - Chemical Engineering and Technology
JF - Chemical Engineering and Technology
IS - 11
ER -