Synthesis and self-assembly of comb-like amphiphilic copolymer poly(maleic anhydride-alt-stearyl methacrylate)-b-poly(stearyl methacrylate)

Junfeng Zhou; Li Wang; Qiang Yang; Xiaochen Dong; Haojie Yu

doi:10.1007/s00396-007-1695-8

Synthesis and self-assembly of comb-like amphiphilic copolymer poly(maleic anhydride-alt-stearyl methacrylate)-b-poly(stearyl methacrylate)

Junfeng Zhou, Li Wang, Qiang Yang, Xiaochen Dong, Haojie Yu

Zhejiang University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Comb-like amphiphilic block copolymers of maleic anhydride (MA) and stearyl methacrylate (SMA) were prepared through the reversible-addition-fragmentation-transfer polymerization. The resultant copolymers were characterized by gel permeation chromatograph and ¹H NMR. The aggregation behaviors of P(MA-alt-SMA)-b-PSMA were investigated in tetrahydrofuran/water. It is of great interest that the aggregates with different morphologies and dimensions could be obtained by adjusting the polymer concentration, water content, and pH. The dimension and structure of these aggregates were investigated by transmission electron microscopy and dynamic light scattering. The effect of the copolymer-solvent interaction on these aggregations was discussed.

Original language	English
Pages (from-to)	1369-1376
Number of pages	8
Journal	Colloid and Polymer Science
Volume	285
Issue number	12
DOIs	https://doi.org/10.1007/s00396-007-1695-8
State	Published - Sep 2007
Externally published	Yes

Keywords

Comb-like amphiphilic copolymer
Maleic anhydride
Self-assembly
Stearyl methacrylate

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10.1007/s00396-007-1695-8

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title = "Synthesis and self-assembly of comb-like amphiphilic copolymer poly(maleic anhydride-alt-stearyl methacrylate)-b-poly(stearyl methacrylate)",

abstract = "Comb-like amphiphilic block copolymers of maleic anhydride (MA) and stearyl methacrylate (SMA) were prepared through the reversible-addition-fragmentation-transfer polymerization. The resultant copolymers were characterized by gel permeation chromatograph and 1H NMR. The aggregation behaviors of P(MA-alt-SMA)-b-PSMA were investigated in tetrahydrofuran/water. It is of great interest that the aggregates with different morphologies and dimensions could be obtained by adjusting the polymer concentration, water content, and pH. The dimension and structure of these aggregates were investigated by transmission electron microscopy and dynamic light scattering. The effect of the copolymer-solvent interaction on these aggregations was discussed.",

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author = "Junfeng Zhou and Li Wang and Qiang Yang and Xiaochen Dong and Haojie Yu",

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doi = "10.1007/s00396-007-1695-8",

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T1 - Synthesis and self-assembly of comb-like amphiphilic copolymer poly(maleic anhydride-alt-stearyl methacrylate)-b-poly(stearyl methacrylate)

AU - Zhou, Junfeng

AU - Wang, Li

AU - Yang, Qiang

AU - Dong, Xiaochen

AU - Yu, Haojie

PY - 2007/9

Y1 - 2007/9

N2 - Comb-like amphiphilic block copolymers of maleic anhydride (MA) and stearyl methacrylate (SMA) were prepared through the reversible-addition-fragmentation-transfer polymerization. The resultant copolymers were characterized by gel permeation chromatograph and 1H NMR. The aggregation behaviors of P(MA-alt-SMA)-b-PSMA were investigated in tetrahydrofuran/water. It is of great interest that the aggregates with different morphologies and dimensions could be obtained by adjusting the polymer concentration, water content, and pH. The dimension and structure of these aggregates were investigated by transmission electron microscopy and dynamic light scattering. The effect of the copolymer-solvent interaction on these aggregations was discussed.

AB - Comb-like amphiphilic block copolymers of maleic anhydride (MA) and stearyl methacrylate (SMA) were prepared through the reversible-addition-fragmentation-transfer polymerization. The resultant copolymers were characterized by gel permeation chromatograph and 1H NMR. The aggregation behaviors of P(MA-alt-SMA)-b-PSMA were investigated in tetrahydrofuran/water. It is of great interest that the aggregates with different morphologies and dimensions could be obtained by adjusting the polymer concentration, water content, and pH. The dimension and structure of these aggregates were investigated by transmission electron microscopy and dynamic light scattering. The effect of the copolymer-solvent interaction on these aggregations was discussed.

KW - Comb-like amphiphilic copolymer

KW - Maleic anhydride

KW - Self-assembly

KW - Stearyl methacrylate

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DO - 10.1007/s00396-007-1695-8

M3 - 文章

AN - SCOPUS:36649032692

SN - 0303-402X

VL - 285

SP - 1369

EP - 1376

JO - Colloid and Polymer Science

JF - Colloid and Polymer Science

IS - 12

ER -

Synthesis and self-assembly of comb-like amphiphilic copolymer poly(maleic anhydride-alt-stearyl methacrylate)-b-poly(stearyl methacrylate)

Abstract

Keywords

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