Synthesis and self-assembly of monodispersed metal-organic framework microcrystals

Guang Lu; Chenlong Cui; Weina Zhang; Yayuan Liu; Fengwei Huo

doi:10.1002/asia.201200754

Synthesis and self-assembly of monodispersed metal-organic framework microcrystals

Guang Lu, Chenlong Cui, Weina Zhang, Yayuan Liu, Fengwei Huo

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

137 Scopus citations

Abstract

How to make super latt(ic)e: Monodispersed octahedral microcrystals of a zirconium-carboxylate metal-organic framework (MOF), UiO-66, were synthesized, under optimized experimental conditions, by using acetic acid as a modulator. Due to their uniform size and shape, the obtained MOF microcrystals can be assembled not only into large-area two-dimensional (2D) monolayers with oriented facets through a liquid-air interfacial assembly technique, but also into long-range three-dimensional (3D) superlattices by sedimentation.

Original language	English
Pages (from-to)	69-72
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	8
Issue number	1
DOIs	https://doi.org/10.1002/asia.201200754
State	Published - Jan 2013
Externally published	Yes

Keywords

crystals
metal-organic frameworks
monolayers
self-assembly
superlattices

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abstract = "How to make super latt(ic)e: Monodispersed octahedral microcrystals of a zirconium-carboxylate metal-organic framework (MOF), UiO-66, were synthesized, under optimized experimental conditions, by using acetic acid as a modulator. Due to their uniform size and shape, the obtained MOF microcrystals can be assembled not only into large-area two-dimensional (2D) monolayers with oriented facets through a liquid-air interfacial assembly technique, but also into long-range three-dimensional (3D) superlattices by sedimentation.",

keywords = "crystals, metal-organic frameworks, monolayers, self-assembly, superlattices",

author = "Guang Lu and Chenlong Cui and Weina Zhang and Yayuan Liu and Fengwei Huo",

year = "2013",

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doi = "10.1002/asia.201200754",

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T1 - Synthesis and self-assembly of monodispersed metal-organic framework microcrystals

AU - Lu, Guang

AU - Cui, Chenlong

AU - Zhang, Weina

AU - Liu, Yayuan

AU - Huo, Fengwei

PY - 2013/1

Y1 - 2013/1

N2 - How to make super latt(ic)e: Monodispersed octahedral microcrystals of a zirconium-carboxylate metal-organic framework (MOF), UiO-66, were synthesized, under optimized experimental conditions, by using acetic acid as a modulator. Due to their uniform size and shape, the obtained MOF microcrystals can be assembled not only into large-area two-dimensional (2D) monolayers with oriented facets through a liquid-air interfacial assembly technique, but also into long-range three-dimensional (3D) superlattices by sedimentation.

AB - How to make super latt(ic)e: Monodispersed octahedral microcrystals of a zirconium-carboxylate metal-organic framework (MOF), UiO-66, were synthesized, under optimized experimental conditions, by using acetic acid as a modulator. Due to their uniform size and shape, the obtained MOF microcrystals can be assembled not only into large-area two-dimensional (2D) monolayers with oriented facets through a liquid-air interfacial assembly technique, but also into long-range three-dimensional (3D) superlattices by sedimentation.

KW - crystals

KW - metal-organic frameworks

KW - monolayers

KW - self-assembly

KW - superlattices

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DO - 10.1002/asia.201200754

M3 - 文章

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SN - 1861-4728

VL - 8

SP - 69

EP - 72

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 1

ER -

Synthesis and self-assembly of monodispersed metal-organic framework microcrystals

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Keywords

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