TY - JOUR
T1 - Synthesis and structure of a novel ion-pair palladium(II) compound containing 2-thioxo-1,3-dithiole-4,5-bis(thiolate)
AU - Huang, Rong Yi
AU - Huang, Liang Fang
AU - Xu, Heng
AU - Liu, Guang Xiang
AU - Ren, Xiao Ming
PY - 2008
Y1 - 2008
N2 - A novel ion-pair palladium(II) compound, (NO2BzPy) 2[Pd(dmit)2] (NO2BzPy+= 1-(4-nitrobenzyl)pyridinium, dmit2- = 2-thioxo-1,3-dithiole-4,5- bis(thiolate)), was synthesized and characterized by single-crystal X-ray structure determination. This compound crystallizes in the monoclinic system, space group P21/n with a = 10.4463(11), b = 8.5627(9), c = 20.017(2) Å, β = 97.7730(10)°, V = 1774.1(3) Å3, Z = 2, C30H22N4O4S10Pd, M r = 929.52, Dc =1.740 g/cm3, μ = 1.155 mm-1, S = 1.006, F(000) = 936, R = 0.0354 and wR = 0.0675. The most intriguing general structural feature of the compound is the completely segregated columnar stacks of anions and cations. There exist hydrogen-bonding interactions within the cation column.
AB - A novel ion-pair palladium(II) compound, (NO2BzPy) 2[Pd(dmit)2] (NO2BzPy+= 1-(4-nitrobenzyl)pyridinium, dmit2- = 2-thioxo-1,3-dithiole-4,5- bis(thiolate)), was synthesized and characterized by single-crystal X-ray structure determination. This compound crystallizes in the monoclinic system, space group P21/n with a = 10.4463(11), b = 8.5627(9), c = 20.017(2) Å, β = 97.7730(10)°, V = 1774.1(3) Å3, Z = 2, C30H22N4O4S10Pd, M r = 929.52, Dc =1.740 g/cm3, μ = 1.155 mm-1, S = 1.006, F(000) = 936, R = 0.0354 and wR = 0.0675. The most intriguing general structural feature of the compound is the completely segregated columnar stacks of anions and cations. There exist hydrogen-bonding interactions within the cation column.
KW - Crystal structure
KW - Dmit
KW - Pd(II) ion-pair compound
UR - http://www.scopus.com/inward/record.url?scp=63849343297&partnerID=8YFLogxK
M3 - 文章
AN - SCOPUS:63849343297
SN - 0254-5861
VL - 27
SP - 1435
EP - 1438
JO - Jiegou Huaxue
JF - Jiegou Huaxue
IS - 12
ER -