Synthesis, crystal structure and luminescent property of coordination polymer [Zn(PDA)(obix)]

Kun Zhu, Huan Min Xu, Guang Xiang Liu, Rong Yi Huang, Xiao Ming Ren

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Hydrothermal reaction between 1,4-phenylenediacetic acid (H 2PDA) and Zn(NO 3) 22 · 6H 20 at the presence of the second ligand of 1,2-bis((l H-imidazol-1 -yl) methyl)benzene (obix) yields a new 2D metal-organic coordination polymer [Zn(PDA)(obix)] (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermal analysis. Complex 1 presents a two-dimensional (2D) sheet structure and displays strong luminescent emission at room temperature. CCDC: 716984.

Original languageEnglish
Pages (from-to)1677-1681
Number of pages5
JournalChinese Journal of Inorganic Chemistry
Volume25
Issue number9
StatePublished - Sep 2009
Externally publishedYes

Keywords

  • Crystal structure
  • Flexible ligand
  • Luminescence
  • Zinc(II) complex

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