Synthesis, crystal structure and luminescent property of one-dimensional chain complex [Cd(FA)(pyim)(H 2O)]

Xue Jun Kong; Kun Zhu; Tian Han Kai; Guang Xiang Liu; Xiao Ming Ren

Synthesis, crystal structure and luminescent property of one-dimensional chain complex [Cd(FA)(pyim)(H ₂O)]

Xue Jun Kong, Kun Zhu, Tian Han Kai, Guang Xiang Liu, Xiao Ming Ren

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H ₂O) (l) (H ₂FA=4, 4'-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO ₃) ₂·4H ₂O, 4, 4'- (hexafluoroisopropylidene)bis (benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O -H · · · O hydrogen-bonds and π...π stacking interactions. The crystal is of monoclinic, space group P2Jn with a=0.856 34(10) nm, b = 1.02049(12) nm, c=2.809 0(3) nm, ß=98.115(2)°, V=2.4302(5) nm ³, D _c= 1.820 g·cm ^-3, Z=4, F(000)=1 320, Goof= 1.009, R ₁ =0.047 0, wR ₂ =0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837.

Original language	English
Pages (from-to)	2193-2196
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	25
Issue number	12
State	Published - Dec 2009
Externally published	Yes

Keywords

Cadmium(II) complex
Crystal structure
Flexible carboxylate ligand
Photoluminescent property

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title = "Synthesis, crystal structure and luminescent property of one-dimensional chain complex [Cd(FA)(pyim)(H 2O)]",

abstract = "A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H 2O) (l) (H 2FA=4, 4'-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO 3) 2·4H 2O, 4, 4'- (hexafluoroisopropylidene)bis (benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O -H · · · O hydrogen-bonds and π...π stacking interactions. The crystal is of monoclinic, space group P2Jn with a=0.856 34(10) nm, b = 1.02049(12) nm, c=2.809 0(3) nm, {\ss}=98.115(2)°, V=2.4302(5) nm 3, D c= 1.820 g·cm -3, Z=4, F(000)=1 320, Goof= 1.009, R 1 =0.047 0, wR 2 =0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837.",

keywords = "Cadmium(II) complex, Crystal structure, Flexible carboxylate ligand, Photoluminescent property",

author = "Kong, {Xue Jun} and Kun Zhu and Kai, {Tian Han} and Liu, {Guang Xiang} and Ren, {Xiao Ming}",

year = "2009",

month = dec,

language = "英语",

volume = "25",

pages = "2193--2196",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

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TY - JOUR

T1 - Synthesis, crystal structure and luminescent property of one-dimensional chain complex [Cd(FA)(pyim)(H 2O)]

AU - Kong, Xue Jun

AU - Zhu, Kun

AU - Kai, Tian Han

AU - Liu, Guang Xiang

AU - Ren, Xiao Ming

PY - 2009/12

Y1 - 2009/12

N2 - A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H 2O) (l) (H 2FA=4, 4'-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO 3) 2·4H 2O, 4, 4'- (hexafluoroisopropylidene)bis (benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O -H · · · O hydrogen-bonds and π...π stacking interactions. The crystal is of monoclinic, space group P2Jn with a=0.856 34(10) nm, b = 1.02049(12) nm, c=2.809 0(3) nm, ß=98.115(2)°, V=2.4302(5) nm 3, D c= 1.820 g·cm -3, Z=4, F(000)=1 320, Goof= 1.009, R 1 =0.047 0, wR 2 =0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837.

AB - A one-dimensional zigzag chain complex of Cd(FA)(pyim)(H 2O) (l) (H 2FA=4, 4'-(hexafluoroisopropylid-ene)bis(benzoic acid) and pyim=2-(2-pyridyl)imidazole) was hydrothermal synthesized from Cd(NO 3) 2·4H 2O, 4, 4'- (hexafluoroisopropylidene)bis (benzoic acid) and 2-(2-pyridyl)imidazole. Single-crystal X-ray analysis revealed that the zigzag chains of 1 are linked into three-dimensional supramolecular networks by both O -H · · · O hydrogen-bonds and π...π stacking interactions. The crystal is of monoclinic, space group P2Jn with a=0.856 34(10) nm, b = 1.02049(12) nm, c=2.809 0(3) nm, ß=98.115(2)°, V=2.4302(5) nm 3, D c= 1.820 g·cm -3, Z=4, F(000)=1 320, Goof= 1.009, R 1 =0.047 0, wR 2 =0.115 5. In addition, complex 1 exhibits strong photoluminescent emission at room temperature. CCDC: 733837.

KW - Cadmium(II) complex

KW - Crystal structure

KW - Flexible carboxylate ligand

KW - Photoluminescent property

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M3 - 文章

AN - SCOPUS:72249100643

SN - 1001-4861

VL - 25

SP - 2193

EP - 2196

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 12

ER -

Synthesis, crystal structure and luminescent property of one-dimensional chain complex [Cd(FA)(pyim)(H ₂O)]

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Keywords

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