Synthesis, crystal structure and magnetic property of a novel ion-pair nickel (III) complex containing 1,2-benzenedithiolate

Guang Xiang Liu; Liang Fang Huang; Xiao Ming Ren

doi:10.1002/aoc.1334

Synthesis, crystal structure and magnetic property of a novel ion-pair nickel (III) complex containing 1,2-benzenedithiolate

Guang Xiang Liu, Liang Fang Huang, Xiao Ming Ren

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

new ion-pair complex [l-(4-nitrobenzyl)pyridinium][Ni(bdt)₂] (1), in which bdt²~ = 1,2benzenedithiolate, has been synthesized and characterized. The X-ray structure analysis shows that the anions are centrosymmetric, the two non-equivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antif erromagnetic exchange system, which may arise from spin-canting.

Original language	English
Pages (from-to)	1054-1058
Number of pages	5
Journal	Applied Organometallic Chemistry
Volume	21
Issue number	12
DOIs	https://doi.org/10.1002/aoc.1334
State	Published - Dec 2007
Externally published	Yes

Keywords

Crystal structure
Magnetism
Nickel(III) thiolate complex
Spin-canting

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10.1002/aoc.1334

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title = "Synthesis, crystal structure and magnetic property of a novel ion-pair nickel (III) complex containing 1,2-benzenedithiolate",

abstract = "new ion-pair complex [l-(4-nitrobenzyl)pyridinium][Ni(bdt)2] (1), in which bdt2~ = 1,2benzenedithiolate, has been synthesized and characterized. The X-ray structure analysis shows that the anions are centrosymmetric, the two non-equivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antif erromagnetic exchange system, which may arise from spin-canting.",

keywords = "Crystal structure, Magnetism, Nickel(III) thiolate complex, Spin-canting",

author = "Liu, {Guang Xiang} and Huang, {Liang Fang} and Ren, {Xiao Ming}",

year = "2007",

month = dec,

doi = "10.1002/aoc.1334",

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volume = "21",

pages = "1054--1058",

journal = "Applied Organometallic Chemistry",

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T1 - Synthesis, crystal structure and magnetic property of a novel ion-pair nickel (III) complex containing 1,2-benzenedithiolate

AU - Liu, Guang Xiang

AU - Huang, Liang Fang

AU - Ren, Xiao Ming

PY - 2007/12

Y1 - 2007/12

N2 - new ion-pair complex [l-(4-nitrobenzyl)pyridinium][Ni(bdt)2] (1), in which bdt2~ = 1,2benzenedithiolate, has been synthesized and characterized. The X-ray structure analysis shows that the anions are centrosymmetric, the two non-equivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antif erromagnetic exchange system, which may arise from spin-canting.

AB - new ion-pair complex [l-(4-nitrobenzyl)pyridinium][Ni(bdt)2] (1), in which bdt2~ = 1,2benzenedithiolate, has been synthesized and characterized. The X-ray structure analysis shows that the anions are centrosymmetric, the two non-equivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antif erromagnetic exchange system, which may arise from spin-canting.

KW - Crystal structure

KW - Magnetism

KW - Nickel(III) thiolate complex

KW - Spin-canting

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U2 - 10.1002/aoc.1334

DO - 10.1002/aoc.1334

M3 - 文章

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SN - 0268-2605

VL - 21

SP - 1054

EP - 1058

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 12

ER -

Synthesis, crystal structure and magnetic property of a novel ion-pair nickel (III) complex containing 1,2-benzenedithiolate

Abstract

Keywords

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