Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5- bis(pyridin-2-yl)-1,2,4-triazole]

Dun Ru Zhu; Tian Wei Wang; Sheng Lai Zhong; Yan Xu; Xiao Zeng You

Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL₂(NCS)₂] [L=4-(p-methylphenyl)-3,5- bis(pyridin-2-yl)-1,2,4-triazole]

Dun Ru Zhu, Tian Wei Wang, Sheng Lai Zhong, Yan Xu, Xiao Zeng You

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A novel manganese(II) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl) -1,2,4-triazole (L), [MnL₂(NCS)₂], has been synthesized and its structure characterized by X-ray crystallography, FT-IR and ESI-MS spectroscopy. In the structure there is an inversion center at the manganese (II) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS^- ions in a trans arrangement. Magnetic measurements show that the complex is high-spin species in the 75-300 K range. CCDC: 234894.

Original language	English
Pages (from-to)	508-512
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	20
Issue number	5
State	Published - 1 May 2004

Keywords

Crystal structure
ESI-MS spectra
Manganese(II) complex
Triazole

Cite this

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title = "Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5- bis(pyridin-2-yl)-1,2,4-triazole]",

abstract = "A novel manganese(II) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl) -1,2,4-triazole (L), [MnL2(NCS)2], has been synthesized and its structure characterized by X-ray crystallography, FT-IR and ESI-MS spectroscopy. In the structure there is an inversion center at the manganese (II) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS- ions in a trans arrangement. Magnetic measurements show that the complex is high-spin species in the 75-300 K range. CCDC: 234894.",

keywords = "Crystal structure, ESI-MS spectra, Manganese(II) complex, Triazole",

author = "Zhu, {Dun Ru} and Wang, {Tian Wei} and Zhong, {Sheng Lai} and Yan Xu and You, {Xiao Zeng}",

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TY - JOUR

T1 - Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5- bis(pyridin-2-yl)-1,2,4-triazole]

AU - Zhu, Dun Ru

AU - Wang, Tian Wei

AU - Zhong, Sheng Lai

AU - Xu, Yan

AU - You, Xiao Zeng

PY - 2004/5/1

Y1 - 2004/5/1

N2 - A novel manganese(II) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl) -1,2,4-triazole (L), [MnL2(NCS)2], has been synthesized and its structure characterized by X-ray crystallography, FT-IR and ESI-MS spectroscopy. In the structure there is an inversion center at the manganese (II) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS- ions in a trans arrangement. Magnetic measurements show that the complex is high-spin species in the 75-300 K range. CCDC: 234894.

AB - A novel manganese(II) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl) -1,2,4-triazole (L), [MnL2(NCS)2], has been synthesized and its structure characterized by X-ray crystallography, FT-IR and ESI-MS spectroscopy. In the structure there is an inversion center at the manganese (II) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS- ions in a trans arrangement. Magnetic measurements show that the complex is high-spin species in the 75-300 K range. CCDC: 234894.

KW - Crystal structure

KW - ESI-MS spectra

KW - Manganese(II) complex

KW - Triazole

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M3 - 文章

AN - SCOPUS:2342606521

SN - 1001-4861

VL - 20

SP - 508

EP - 512

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 5

ER -

Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL₂(NCS)₂] [L=4-(p-methylphenyl)-3,5- bis(pyridin-2-yl)-1,2,4-triazole]

Abstract

Keywords

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