TY - JOUR
T1 - Synthesis, crystal structure and magnetic property of the novel dinuclear nickel(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridine-2-yl)-1,2,4- triazole
AU - Zhou, Jun
AU - Yang, Jie
AU - Qi, Li
AU - Shen, Xuan
AU - Zhu, Dunru
AU - Xu, Yan
AU - Song, You
PY - 2007/9
Y1 - 2007/9
N2 - A novel dinuclear nickel(II) complex, [Ni2(MOBPT) 2Cl2(H2O)2]Cl2̇ 7H2O (MOBPT = 4-(p-methoxyphenyl) -3,5-bis(pyridine-2-yl)-1,2,4- triazole), has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction methods. The crystal structure determination shows that the dinuclear Ni2N8 unit is almost planer in which each NiII ion is coordinated by four nitrogen atoms from MOBPT equatorially and a water molecule and a chloride ion axially in a distorted octahedral geometry. Magnetic measurements reveal a relatively weak antiferromagnetic exchange in the complex.
AB - A novel dinuclear nickel(II) complex, [Ni2(MOBPT) 2Cl2(H2O)2]Cl2̇ 7H2O (MOBPT = 4-(p-methoxyphenyl) -3,5-bis(pyridine-2-yl)-1,2,4- triazole), has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction methods. The crystal structure determination shows that the dinuclear Ni2N8 unit is almost planer in which each NiII ion is coordinated by four nitrogen atoms from MOBPT equatorially and a water molecule and a chloride ion axially in a distorted octahedral geometry. Magnetic measurements reveal a relatively weak antiferromagnetic exchange in the complex.
UR - http://www.scopus.com/inward/record.url?scp=34547587034&partnerID=8YFLogxK
U2 - 10.1007/s11243-007-0234-2
DO - 10.1007/s11243-007-0234-2
M3 - 文章
AN - SCOPUS:34547587034
SN - 0340-4285
VL - 32
SP - 711
EP - 715
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 6
ER -