Synthesis, crystal structure and magnetic studies of cis-configuration copper(II)-M(II) (M = Ba, Ca) complexes of novel Schiff bases derived from salicylaldehyde and dipeptides

Chuan Jing Hu; Xiao Ming Ren; Chang Sheng Lu; Yang Zou; Wen Wei Zhang; Chun Ying Duan; Qing Jin Meng; Hua Qin Wang

doi:10.1023/A:1022950908945

Synthesis, crystal structure and magnetic studies of cis-configuration copper(II)-M(II) (M = Ba, Ca) complexes of novel Schiff bases derived from salicylaldehyde and dipeptides

Chuan Jing Hu, Xiao Ming Ren, Chang Sheng Lu, Yang Zou, Wen Wei Zhang, Chun Ying Duan, Qing Jin Meng, Hua Qin Wang

Nanjing University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The novel heteronuclear complexes [M(CuL)₂]₂ · nH₂O [M = Ba (I), Ca (2); H₂L = N-salicylideneglycylglycine] were synthesized and characterized, and the crystal structure of complex (I) was determined by X-ray diffraction The entire structure is held together by an extensive network of H-bonds and π-π interactions. Variable-temperature magnetic susceptibility measurement (75-300 K) revealed the occurrence of an intramolecular antiferromagnetic interaction in (1) and (2).

Original language	English
Pages (from-to)	350-355
Number of pages	6
Journal	Transition Metal Chemistry
Volume	28
Issue number	3
DOIs	https://doi.org/10.1023/A:1022950908945
State	Published - Apr 2003
Externally published	Yes

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@article{e81f0fcd2bd34d7e96683edc36086fce,

title = "Synthesis, crystal structure and magnetic studies of cis-configuration copper(II)-M(II) (M = Ba, Ca) complexes of novel Schiff bases derived from salicylaldehyde and dipeptides",

abstract = "The novel heteronuclear complexes [M(CuL)2]2 · nH2O [M = Ba (I), Ca (2); H2L = N-salicylideneglycylglycine] were synthesized and characterized, and the crystal structure of complex (I) was determined by X-ray diffraction The entire structure is held together by an extensive network of H-bonds and π-π interactions. Variable-temperature magnetic susceptibility measurement (75-300 K) revealed the occurrence of an intramolecular antiferromagnetic interaction in (1) and (2).",

author = "Hu, {Chuan Jing} and Ren, {Xiao Ming} and Lu, {Chang Sheng} and Yang Zou and Zhang, {Wen Wei} and Duan, {Chun Ying} and Meng, {Qing Jin} and Wang, {Hua Qin}",

year = "2003",

month = apr,

doi = "10.1023/A:1022950908945",

language = "英语",

volume = "28",

pages = "350--355",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "3",

}

Synthesis, crystal structure and magnetic studies of cis-configuration copper(II)-M(II) (M = Ba, Ca) complexes of novel Schiff bases derived from salicylaldehyde and dipeptides. / Hu, Chuan Jing; Ren, Xiao Ming; Lu, Chang Sheng et al.
In: Transition Metal Chemistry, Vol. 28, No. 3, 04.2003, p. 350-355.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, crystal structure and magnetic studies of cis-configuration copper(II)-M(II) (M = Ba, Ca) complexes of novel Schiff bases derived from salicylaldehyde and dipeptides

AU - Hu, Chuan Jing

AU - Ren, Xiao Ming

AU - Lu, Chang Sheng

AU - Zou, Yang

AU - Zhang, Wen Wei

AU - Duan, Chun Ying

AU - Meng, Qing Jin

AU - Wang, Hua Qin

PY - 2003/4

Y1 - 2003/4

N2 - The novel heteronuclear complexes [M(CuL)2]2 · nH2O [M = Ba (I), Ca (2); H2L = N-salicylideneglycylglycine] were synthesized and characterized, and the crystal structure of complex (I) was determined by X-ray diffraction The entire structure is held together by an extensive network of H-bonds and π-π interactions. Variable-temperature magnetic susceptibility measurement (75-300 K) revealed the occurrence of an intramolecular antiferromagnetic interaction in (1) and (2).

AB - The novel heteronuclear complexes [M(CuL)2]2 · nH2O [M = Ba (I), Ca (2); H2L = N-salicylideneglycylglycine] were synthesized and characterized, and the crystal structure of complex (I) was determined by X-ray diffraction The entire structure is held together by an extensive network of H-bonds and π-π interactions. Variable-temperature magnetic susceptibility measurement (75-300 K) revealed the occurrence of an intramolecular antiferromagnetic interaction in (1) and (2).

UR - http://www.scopus.com/inward/record.url?scp=0038005428&partnerID=8YFLogxK

U2 - 10.1023/A:1022950908945

DO - 10.1023/A:1022950908945

M3 - 文章

AN - SCOPUS:0038005428

SN - 0340-4285

VL - 28

SP - 350

EP - 355

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 3

ER -

Synthesis, crystal structure and magnetic studies of cis-configuration copper(II)-M(II) (M = Ba, Ca) complexes of novel Schiff bases derived from salicylaldehyde and dipeptides

Abstract

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