Synthesis, crystal structure, and properties of [Cu(LH)]2[M(mnt)2] [M = Ni or Cu; H2L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt2- = maleonitriledithiolate] complexes containing bridging cyano groups

Xiaoming Ren; Chunying Duan; Huizhen Zhu; Qingjin Meng; Chuanjiang Hu; Changsheng Lu; Yongjiang Liu

doi:10.1023/A:1007124709040

Synthesis, crystal structure, and properties of [Cu(LH)]₂[M(mnt)₂] [M = Ni or Cu; H₂L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt^2- = maleonitriledithiolate] complexes containing bridging cyano groups

Xiaoming Ren, Chunying Duan, Huizhen Zhu, Qingjin Meng, Chuanjiang Hu, Changsheng Lu, Yongjiang Liu

Nanjing University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Interesting complexes containing a mnt^2- bridge, based on the reaction of [M(mnt)₂]^2- [M = Ni or Cu] with [Cu(LH)]⁺, have been prepared and characterized by e.s.m.s., i.r and u.v-vis, spectroscopic techniques and by electrochemistry. The complexes show weak antiferromagnetic interactions between magnetic centers. The X-ray analysis of the molecular structure of [Cu(LH)]₂[Ni(mnt)₂] has been completed. It structurally features the CN group of mnt^2-which can act as a bridging ligand between two transition metals.

Original language	English
Pages (from-to)	295-299
Number of pages	5
Journal	Transition Metal Chemistry
Volume	26
Issue number	3
DOIs	https://doi.org/10.1023/A:1007124709040
State	Published - Jun 2001
Externally published	Yes

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Ren, X., Duan, C., Zhu, H., Meng, Q., Hu, C., Lu, C., & Liu, Y. (2001). Synthesis, crystal structure, and properties of [Cu(LH)]₂[M(mnt)₂] [M = Ni or Cu; H₂L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt^2- = maleonitriledithiolate] complexes containing bridging cyano groups. Transition Metal Chemistry, 26(3), 295-299. https://doi.org/10.1023/A:1007124709040

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title = "Synthesis, crystal structure, and properties of [Cu(LH)]2[M(mnt)2] [M = Ni or Cu; H2L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt2- = maleonitriledithiolate] complexes containing bridging cyano groups",

abstract = "Interesting complexes containing a mnt2- bridge, based on the reaction of [M(mnt)2]2- [M = Ni or Cu] with [Cu(LH)]+, have been prepared and characterized by e.s.m.s., i.r and u.v-vis, spectroscopic techniques and by electrochemistry. The complexes show weak antiferromagnetic interactions between magnetic centers. The X-ray analysis of the molecular structure of [Cu(LH)]2[Ni(mnt)2] has been completed. It structurally features the CN group of mnt2-which can act as a bridging ligand between two transition metals.",

author = "Xiaoming Ren and Chunying Duan and Huizhen Zhu and Qingjin Meng and Chuanjiang Hu and Changsheng Lu and Yongjiang Liu",

year = "2001",

month = jun,

doi = "10.1023/A:1007124709040",

language = "英语",

volume = "26",

pages = "295--299",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

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Ren, X, Duan, C, Zhu, H, Meng, Q, Hu, C, Lu, C & Liu, Y 2001, 'Synthesis, crystal structure, and properties of [Cu(LH)]₂[M(mnt)₂] [M = Ni or Cu; H₂L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt^2- = maleonitriledithiolate] complexes containing bridging cyano groups', Transition Metal Chemistry, vol. 26, no. 3, pp. 295-299. https://doi.org/10.1023/A:1007124709040

Synthesis, crystal structure, and properties of [Cu(LH)]₂[M(mnt)₂] [M = Ni or Cu; H₂L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt^2- = maleonitriledithiolate] complexes containing bridging cyano groups. / Ren, Xiaoming; Duan, Chunying; Zhu, Huizhen et al.
In: Transition Metal Chemistry, Vol. 26, No. 3, 06.2001, p. 295-299.

Research output: Contribution to journal › Article › peer-review

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T1 - Synthesis, crystal structure, and properties of [Cu(LH)]2[M(mnt)2] [M = Ni or Cu; H2L = 3,3′-(1,3-propanediyldinitrilo)-bis(2-butanone oxime); mnt2- = maleonitriledithiolate] complexes containing bridging cyano groups

AU - Ren, Xiaoming

AU - Duan, Chunying

AU - Zhu, Huizhen

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AU - Hu, Chuanjiang

AU - Lu, Changsheng

AU - Liu, Yongjiang

PY - 2001/6

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AB - Interesting complexes containing a mnt2- bridge, based on the reaction of [M(mnt)2]2- [M = Ni or Cu] with [Cu(LH)]+, have been prepared and characterized by e.s.m.s., i.r and u.v-vis, spectroscopic techniques and by electrochemistry. The complexes show weak antiferromagnetic interactions between magnetic centers. The X-ray analysis of the molecular structure of [Cu(LH)]2[Ni(mnt)2] has been completed. It structurally features the CN group of mnt2-which can act as a bridging ligand between two transition metals.

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