TY - JOUR
T1 - Synthesis, crystal structure and thermal stability of [CuL2(C1O4)2] (l=3-(p-bromopheny1)-4-(p-methy1pheny1)-5-(2-pyridy1)-1,2,4-triazo1e)
AU - Chen, Lang
AU - Cheng, Hui Min
AU - Jiang, Jing Jing
AU - Shen, Xuan
AU - Zhu, Dun Ru
PY - 2012/2
Y1 - 2012/2
N2 - A copper(II) complex, trans-[CuL2(Cl04)2], (L=3-(p-bromophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TGA/DSC and X-ray crystallography. The complex crystallizes in triclinic system with space group P1̄, a=0.829 29(15) nm, b =0.854 48(16) nm, c=1.502 7(3) nm, α=83.517(2)°, β =89.200(2)°, γ=73.064(2)°, V=1.011 9(3) nm3, Z=1 and final, R=0.041 2. The copper atom lies in a distorted octahedral environment with two Cl04- ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 310 °C.
AB - A copper(II) complex, trans-[CuL2(Cl04)2], (L=3-(p-bromophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TGA/DSC and X-ray crystallography. The complex crystallizes in triclinic system with space group P1̄, a=0.829 29(15) nm, b =0.854 48(16) nm, c=1.502 7(3) nm, α=83.517(2)°, β =89.200(2)°, γ=73.064(2)°, V=1.011 9(3) nm3, Z=1 and final, R=0.041 2. The copper atom lies in a distorted octahedral environment with two Cl04- ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 310 °C.
KW - 1,2,4-triazole
KW - Crystal structure
KW - Cu(II) complex
UR - http://www.scopus.com/inward/record.url?scp=84863071933&partnerID=8YFLogxK
M3 - 文章
AN - SCOPUS:84863071933
SN - 1001-4861
VL - 28
SP - 381
EP - 385
JO - Chinese Journal of Inorganic Chemistry
JF - Chinese Journal of Inorganic Chemistry
IS - 2
ER -