TY - JOUR
T1 - Synthesis, crystal structures, and photoluminescence of two novel zinc coordination polymers built from 2,2'-(ethyne-1,2-diyl)diterephthalate
AU - Hu, Yun Xia
AU - Wang, Li Feng
AU - Zhang, Wen Wei
AU - Li, Yi Zhi
AU - Ren, Xiao Ming
AU - Bai, Junfeng
PY - 2012/3
Y1 - 2012/3
N2 - Two coordination polymers, [Zn(EDDT) 0.5(H 2O) 2] (1) and [Zn(EDDT) 0.5(BPE)]·xG (2) (EDDT = 2,2'-(ethyne-1,2-diyl)diterephthalate, BPE = 1,2-bi(4-pyridyl)ethane, G = guest molecule), were solvothermally synthesized from the rigid planar linker of EDDT and the coligand of BPE, respectively, in which complex 1 displays 2D [Zn(EDDT) 0.5] coordination layer, and the resulting 3D supramolecular network is formed via interlayer H-bonding interactions, whereas complex 2 exhibits an intriguing micropourous framework via the coordination of auxiliary ligand BPE. Interestingly, both of them show enhanced strong blue luminescence.
AB - Two coordination polymers, [Zn(EDDT) 0.5(H 2O) 2] (1) and [Zn(EDDT) 0.5(BPE)]·xG (2) (EDDT = 2,2'-(ethyne-1,2-diyl)diterephthalate, BPE = 1,2-bi(4-pyridyl)ethane, G = guest molecule), were solvothermally synthesized from the rigid planar linker of EDDT and the coligand of BPE, respectively, in which complex 1 displays 2D [Zn(EDDT) 0.5] coordination layer, and the resulting 3D supramolecular network is formed via interlayer H-bonding interactions, whereas complex 2 exhibits an intriguing micropourous framework via the coordination of auxiliary ligand BPE. Interestingly, both of them show enhanced strong blue luminescence.
KW - 2,2'-(Ethyne-1,2-diyl)diterephthalate
KW - Coordination polymers
KW - Luminescence properties
KW - Solvothermal synthesis
KW - Zn(II) complex
UR - http://www.scopus.com/inward/record.url?scp=84862831184&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2011.12.048
DO - 10.1016/j.inoche.2011.12.048
M3 - 文章
AN - SCOPUS:84862831184
SN - 1387-7003
VL - 17
SP - 173
EP - 176
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -