Abstract
The new rigid bicyclic AMPP((S)-TIAMPP) has been synthesized from the corresponding Ticol and Ph2PCl. The application of (S)-TIAMPP in Rh-catalyzed asymmetric hydrogenation of α-dehydroamino acids derivatives has been examined. Up to 93% ee was obtained.
Original language | English |
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Pages (from-to) | 1169-1172 |
Number of pages | 4 |
Journal | Chinese Chemical Letters |
Volume | 16 |
Issue number | 9 |
DOIs | |
State | Published - Sep 2005 |
Keywords
- (S)-TIAMPP
- Asymmetric hydrogenation
- Synthesis