Synthesis of nanosphere-like LiCoPO4 with excellent electrochemical performance via micro reactor assisted co-precipitation method

Huifang Zhao; Yong Yu; Guojing Wang; Yunchao Chen; Xiaomin Liu; Hui Yang

doi:10.1142/S1793604718500376

Synthesis of nanosphere-like LiCoPO₄ with excellent electrochemical performance via micro reactor assisted co-precipitation method

Huifang Zhao, Yong Yu, Guojing Wang, Yunchao Chen, Xiaomin Liu, Hui Yang

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Li₃PO₄ and Co₃(PO₄)₂?8H₂O precursors, precipitated within a micro reactor using ethyl alcohol as anti-solvent, are sintered to form nanosphere-like LiCoPO₄. Even without carbon coating, the resulting sample with 2.1wt.% Li₃PO₄ existence presents surprisingly high initial discharge capacity (up to 164mAh/g and 787Wh/kg at 0.1C) and superior high rate performance (117mAh/g and 561Wh/kg at 5C).

Original language	English
Article number	1850037
Journal	Functional Materials Letters
Volume	11
Issue number	5
DOIs	https://doi.org/10.1142/S1793604718500376
State	Published - 1 Oct 2018

Keywords

LiCoPO
high energy density
micro reactor

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title = "Synthesis of nanosphere-like LiCoPO4 with excellent electrochemical performance via micro reactor assisted co-precipitation method",

abstract = "Li3PO4 and Co3(PO4)2?8H2O precursors, precipitated within a micro reactor using ethyl alcohol as anti-solvent, are sintered to form nanosphere-like LiCoPO4. Even without carbon coating, the resulting sample with 2.1wt.% Li3PO4 existence presents surprisingly high initial discharge capacity (up to 164mAh/g and 787Wh/kg at 0.1C) and superior high rate performance (117mAh/g and 561Wh/kg at 5C).",

keywords = "LiCoPO, high energy density, micro reactor",

author = "Huifang Zhao and Yong Yu and Guojing Wang and Yunchao Chen and Xiaomin Liu and Hui Yang",

note = "Publisher Copyright: {\textcopyright} 2018 World Scientific Publishing Company.",

year = "2018",

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doi = "10.1142/S1793604718500376",

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T1 - Synthesis of nanosphere-like LiCoPO4 with excellent electrochemical performance via micro reactor assisted co-precipitation method

AU - Zhao, Huifang

AU - Yu, Yong

AU - Wang, Guojing

AU - Chen, Yunchao

AU - Liu, Xiaomin

AU - Yang, Hui

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Li3PO4 and Co3(PO4)2?8H2O precursors, precipitated within a micro reactor using ethyl alcohol as anti-solvent, are sintered to form nanosphere-like LiCoPO4. Even without carbon coating, the resulting sample with 2.1wt.% Li3PO4 existence presents surprisingly high initial discharge capacity (up to 164mAh/g and 787Wh/kg at 0.1C) and superior high rate performance (117mAh/g and 561Wh/kg at 5C).

AB - Li3PO4 and Co3(PO4)2?8H2O precursors, precipitated within a micro reactor using ethyl alcohol as anti-solvent, are sintered to form nanosphere-like LiCoPO4. Even without carbon coating, the resulting sample with 2.1wt.% Li3PO4 existence presents surprisingly high initial discharge capacity (up to 164mAh/g and 787Wh/kg at 0.1C) and superior high rate performance (117mAh/g and 561Wh/kg at 5C).

KW - LiCoPO

KW - high energy density

KW - micro reactor

UR - http://www.scopus.com/inward/record.url?scp=85046032845&partnerID=8YFLogxK

U2 - 10.1142/S1793604718500376

DO - 10.1142/S1793604718500376

M3 - 文章

AN - SCOPUS:85046032845

SN - 1793-6047

VL - 11

JO - Functional Materials Letters

JF - Functional Materials Letters

IS - 5

M1 - 1850037

ER -

Synthesis of nanosphere-like LiCoPO₄ with excellent electrochemical performance via micro reactor assisted co-precipitation method

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Keywords

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