Synthesis of titania-pillared layered niobic acid with a high specific surface area by using sol-intercalation method

Xian Ji Guo; Wen Hua Hou; Yan Kong; Chun Liang Lu; Tian Yang Yao; Qi Jie Yan

Synthesis of titania-pillared layered niobic acid with a high specific surface area by using sol-intercalation method

Xian Ji Guo, Wen Hua Hou, Yan Kong, Chun Liang Lu, Tian Yang Yao, Qi Jie Yan

Nanjing University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Hydrated titanium sol particles-intercalated layered niobate was prepared through the reaction between n-decylamine-intercalated niobate and hydrated product of tetrabutyl titanate. The titania-pillared layered niobic acid then obtained by calcining the titanium sol particles-intercalated niobate at 450°C in air. The resulting material has been characterized by means of XRD, IR, BET surface area and pore size distribution measurement techniques. The pillared sample was porous (mainly mesopores), with a high BET surface area of 131.3m²·g^-1 and an interlayer distance of 1.26nm at 450°C. Test of thermal stability revealed that the structure of the titania-pillared layered niobic acid was stable after this material calcined at 550°C for 2h in air.

Original language	English
Pages (from-to)	273-277
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	3
State	Published - 1 Mar 2003
Externally published	Yes

Keywords

Layered niobic acid
Pillaring
Sol-intercalation method
Titania

Cite this

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title = "Synthesis of titania-pillared layered niobic acid with a high specific surface area by using sol-intercalation method",

abstract = "Hydrated titanium sol particles-intercalated layered niobate was prepared through the reaction between n-decylamine-intercalated niobate and hydrated product of tetrabutyl titanate. The titania-pillared layered niobic acid then obtained by calcining the titanium sol particles-intercalated niobate at 450°C in air. The resulting material has been characterized by means of XRD, IR, BET surface area and pore size distribution measurement techniques. The pillared sample was porous (mainly mesopores), with a high BET surface area of 131.3m2·g-1 and an interlayer distance of 1.26nm at 450°C. Test of thermal stability revealed that the structure of the titania-pillared layered niobic acid was stable after this material calcined at 550°C for 2h in air.",

keywords = "Layered niobic acid, Pillaring, Sol-intercalation method, Titania",

author = "Guo, {Xian Ji} and Hou, {Wen Hua} and Yan Kong and Lu, {Chun Liang} and Yao, {Tian Yang} and Yan, {Qi Jie}",

year = "2003",

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pages = "273--277",

journal = "Chinese Journal of Inorganic Chemistry",

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TY - JOUR

T1 - Synthesis of titania-pillared layered niobic acid with a high specific surface area by using sol-intercalation method

AU - Guo, Xian Ji

AU - Hou, Wen Hua

AU - Kong, Yan

AU - Lu, Chun Liang

AU - Yao, Tian Yang

AU - Yan, Qi Jie

PY - 2003/3/1

Y1 - 2003/3/1

N2 - Hydrated titanium sol particles-intercalated layered niobate was prepared through the reaction between n-decylamine-intercalated niobate and hydrated product of tetrabutyl titanate. The titania-pillared layered niobic acid then obtained by calcining the titanium sol particles-intercalated niobate at 450°C in air. The resulting material has been characterized by means of XRD, IR, BET surface area and pore size distribution measurement techniques. The pillared sample was porous (mainly mesopores), with a high BET surface area of 131.3m2·g-1 and an interlayer distance of 1.26nm at 450°C. Test of thermal stability revealed that the structure of the titania-pillared layered niobic acid was stable after this material calcined at 550°C for 2h in air.

AB - Hydrated titanium sol particles-intercalated layered niobate was prepared through the reaction between n-decylamine-intercalated niobate and hydrated product of tetrabutyl titanate. The titania-pillared layered niobic acid then obtained by calcining the titanium sol particles-intercalated niobate at 450°C in air. The resulting material has been characterized by means of XRD, IR, BET surface area and pore size distribution measurement techniques. The pillared sample was porous (mainly mesopores), with a high BET surface area of 131.3m2·g-1 and an interlayer distance of 1.26nm at 450°C. Test of thermal stability revealed that the structure of the titania-pillared layered niobic acid was stable after this material calcined at 550°C for 2h in air.

KW - Layered niobic acid

KW - Pillaring

KW - Sol-intercalation method

KW - Titania

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M3 - 文章

AN - SCOPUS:0141626967

SN - 1001-4861

VL - 19

SP - 273

EP - 277

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 3

ER -

Synthesis of titania-pillared layered niobic acid with a high specific surface area by using sol-intercalation method

Abstract

Keywords

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