Synthesis, structure and magnetic property of coordination polymer Cu(N3)2(C6H8N2) n with 1D chain

Kang Shen; Dun Ru Zhu; Yan Fei Wu; Xuan Shen

Synthesis, structure and magnetic property of coordination polymer Cu(N₃)₂(C₆H₈N₂) _n with 1D chain

Kang Shen, Dun Ru Zhu, Yan Fei Wu, Xuan Shen

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A new one-dimensional chain complex [Cu(N₃)₂(C ₆H₈N₂)]_n (C₆H ₈N₂=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm³, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(II) ions.

Original language	English
Pages (from-to)	1912-1915
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	24
Issue number	11
State	Published - Nov 2008

Keywords

Azido-bridged
Copper(II) complex
Crystal structure
Magnetic property

Cite this

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title = "Synthesis, structure and magnetic property of coordination polymer Cu(N3)2(C6H8N2) n with 1D chain",

abstract = "A new one-dimensional chain complex [Cu(N3)2(C 6H8N2)]n (C6H 8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(II) ions.",

keywords = "Azido-bridged, Copper(II) complex, Crystal structure, Magnetic property",

author = "Kang Shen and Zhu, {Dun Ru} and Wu, {Yan Fei} and Xuan Shen",

year = "2008",

month = nov,

language = "英语",

volume = "24",

pages = "1912--1915",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "11",

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TY - JOUR

T1 - Synthesis, structure and magnetic property of coordination polymer Cu(N3)2(C6H8N2) n with 1D chain

AU - Shen, Kang

AU - Zhu, Dun Ru

AU - Wu, Yan Fei

AU - Shen, Xuan

PY - 2008/11

Y1 - 2008/11

N2 - A new one-dimensional chain complex [Cu(N3)2(C 6H8N2)]n (C6H 8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(II) ions.

AB - A new one-dimensional chain complex [Cu(N3)2(C 6H8N2)]n (C6H 8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(II) ions.

KW - Azido-bridged

KW - Copper(II) complex

KW - Crystal structure

KW - Magnetic property

UR - http://www.scopus.com/inward/record.url?scp=56749163332&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:56749163332

SN - 1001-4861

VL - 24

SP - 1912

EP - 1915

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 11

ER -

Synthesis, structure and magnetic property of coordination polymer Cu(N₃)₂(C₆H₈N₂) _n with 1D chain

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Keywords

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