Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(III) coordination polymer

Guangxiang Liu; Hong Zhou; Xiaoming Ren

doi:10.1016/S1002-0721(10)60606-0

Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(III) coordination polymer

Guangxiang Liu, Hong Zhou, Xiaoming Ren

School of Chemistry and Moleculai Engineering

Nanjing Xiaozhuang College

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A novel coordination polymer, [Pr₂(BIPA)₃(H ₂O)₂]·2H₂O (1) (H₂BIPA=5- bromoisophthalic acid), was prepared by hydrothermal synthesis and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal was of monoclinic system, space group C2/c, with a=1.98037(14), b=1.44189(14), c=2.15281(18) nm, β=95.220(2)°, V=6.1218(9) nm ³, C₂₄H₁₇Br₃O₁₆Pr ₂, M_r=1082.93, D_c= 2.350 g/cm³, F(000)=4096, μ=7.136 mm^-1 and Z=8. The final R₁=0.0608 and wR₂=0.1371 for 5624 observed reflections (I>2σ(I)). Complex 1 featured an interesting 2D layer containing {Pr₂(CO ₂)₃}_n right-handed and left-handed helical chains. Furthermore, hydrogen bonds linked the adjacent 2D layers to form a 3D supramolecular framework. Moreover, the near-infrared luminescent properties of 1 were also investigated in the solid state.

Original language	English
Pages (from-to)	1100-1104
Number of pages	5
Journal	Journal of Rare Earths
Volume	29
Issue number	11
DOIs	https://doi.org/10.1016/S1002-0721(10)60606-0
State	Published - Nov 2011

Keywords

5-bromoisophthalic acid
Pr(III) coordination polymer
crystal structure
near-infrared luminescence
rare earths

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10.1016/S1002-0721(10)60606-0

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@article{dda83a386b0d47d4a30c4297ebf5a454,

title = "Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(III) coordination polymer",

abstract = "A novel coordination polymer, [Pr2(BIPA)3(H 2O)2]·2H2O (1) (H2BIPA=5- bromoisophthalic acid), was prepared by hydrothermal synthesis and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal was of monoclinic system, space group C2/c, with a=1.98037(14), b=1.44189(14), c=2.15281(18) nm, β=95.220(2)°, V=6.1218(9) nm 3, C24H17Br3O16Pr 2, Mr=1082.93, Dc= 2.350 g/cm3, F(000)=4096, μ=7.136 mm-1 and Z=8. The final R1=0.0608 and wR2=0.1371 for 5624 observed reflections (I>2σ(I)). Complex 1 featured an interesting 2D layer containing {Pr2(CO 2)3}n right-handed and left-handed helical chains. Furthermore, hydrogen bonds linked the adjacent 2D layers to form a 3D supramolecular framework. Moreover, the near-infrared luminescent properties of 1 were also investigated in the solid state.",

keywords = "5-bromoisophthalic acid, Pr(III) coordination polymer, crystal structure, near-infrared luminescence, rare earths",

author = "Guangxiang Liu and Hong Zhou and Xiaoming Ren",

year = "2011",

month = nov,

doi = "10.1016/S1002-0721(10)60606-0",

language = "英语",

volume = "29",

pages = "1100--1104",

journal = "Journal of Rare Earths",

issn = "1002-0721",

publisher = "Editorial Office of Chinese Rare Earths",

number = "11",

}

TY - JOUR

T1 - Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(III) coordination polymer

AU - Liu, Guangxiang

AU - Zhou, Hong

AU - Ren, Xiaoming

PY - 2011/11

Y1 - 2011/11

N2 - A novel coordination polymer, [Pr2(BIPA)3(H 2O)2]·2H2O (1) (H2BIPA=5- bromoisophthalic acid), was prepared by hydrothermal synthesis and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal was of monoclinic system, space group C2/c, with a=1.98037(14), b=1.44189(14), c=2.15281(18) nm, β=95.220(2)°, V=6.1218(9) nm 3, C24H17Br3O16Pr 2, Mr=1082.93, Dc= 2.350 g/cm3, F(000)=4096, μ=7.136 mm-1 and Z=8. The final R1=0.0608 and wR2=0.1371 for 5624 observed reflections (I>2σ(I)). Complex 1 featured an interesting 2D layer containing {Pr2(CO 2)3}n right-handed and left-handed helical chains. Furthermore, hydrogen bonds linked the adjacent 2D layers to form a 3D supramolecular framework. Moreover, the near-infrared luminescent properties of 1 were also investigated in the solid state.

AB - A novel coordination polymer, [Pr2(BIPA)3(H 2O)2]·2H2O (1) (H2BIPA=5- bromoisophthalic acid), was prepared by hydrothermal synthesis and characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal was of monoclinic system, space group C2/c, with a=1.98037(14), b=1.44189(14), c=2.15281(18) nm, β=95.220(2)°, V=6.1218(9) nm 3, C24H17Br3O16Pr 2, Mr=1082.93, Dc= 2.350 g/cm3, F(000)=4096, μ=7.136 mm-1 and Z=8. The final R1=0.0608 and wR2=0.1371 for 5624 observed reflections (I>2σ(I)). Complex 1 featured an interesting 2D layer containing {Pr2(CO 2)3}n right-handed and left-handed helical chains. Furthermore, hydrogen bonds linked the adjacent 2D layers to form a 3D supramolecular framework. Moreover, the near-infrared luminescent properties of 1 were also investigated in the solid state.

KW - 5-bromoisophthalic acid

KW - Pr(III) coordination polymer

KW - crystal structure

KW - near-infrared luminescence

KW - rare earths

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U2 - 10.1016/S1002-0721(10)60606-0

DO - 10.1016/S1002-0721(10)60606-0

M3 - 文章

AN - SCOPUS:83455228469

SN - 1002-0721

VL - 29

SP - 1100

EP - 1104

JO - Journal of Rare Earths

JF - Journal of Rare Earths

IS - 11

ER -

Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(III) coordination polymer

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