The [B3(NN)3]+ and [B3(CO)3]+ Complexes Featuring the Smallest π-Aromatic Species B3+

Jiaye Jin; Guanjun Wang; Mingfei Zhou; Diego M. Andrada; Markus Hermann; Gernot Frenking

doi:10.1002/anie.201509826

The [B₃(NN)₃]⁺ and [B₃(CO)₃]⁺ Complexes Featuring the Smallest π-Aromatic Species B₃⁺

Jiaye Jin, Guanjun Wang, Mingfei Zhou, Diego M. Andrada, Markus Hermann, Gernot Frenking

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

We report the spectroscopic identification of the [B₃(NN)₃]⁺ and [B₃(CO)₃]⁺ complexes, which feature the smallest π-aromatic system B₃⁺. A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B₃L₂]⁺ σ-donation. Minimal π systems: The [B₃(NN)₃]⁺ and [B₃(CO)₃]⁺ complexes are identified through infrared photodissociation spectroscopy. The complexes feature the smallest π-aromatic system B₃⁺. Quantum chemical bonding analysis reveals that the adducts are stabilized by L→[B₃L₂]⁺ σ-donation.

Original language	English
Pages (from-to)	2078-2082
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	6
DOIs	https://doi.org/10.1002/anie.201509826
State	Published - 5 Feb 2016
Externally published	Yes

Keywords

aromaticity
bonding analysis
coordination chemistry
photodissociation
physical chemistry

Access to Document

10.1002/anie.201509826

Cite this

@article{f1f3d8ca116643c39be191baf137d0d3,

title = "The [B3(NN)3]+ and [B3(CO)3]+ Complexes Featuring the Smallest π-Aromatic Species B3+",

abstract = "We report the spectroscopic identification of the [B3(NN)3]+ and [B3(CO)3]+ complexes, which feature the smallest π-aromatic system B3+. A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3L2]+ σ-donation. Minimal π systems: The [B3(NN)3]+ and [B3(CO)3]+ complexes are identified through infrared photodissociation spectroscopy. The complexes feature the smallest π-aromatic system B3+. Quantum chemical bonding analysis reveals that the adducts are stabilized by L→[B3L2]+ σ-donation.",

keywords = "aromaticity, bonding analysis, coordination chemistry, photodissociation, physical chemistry",

author = "Jiaye Jin and Guanjun Wang and Mingfei Zhou and Andrada, {Diego M.} and Markus Hermann and Gernot Frenking",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2016",

month = feb,

day = "5",

doi = "10.1002/anie.201509826",

language = "英语",

volume = "55",

pages = "2078--2082",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "6",

}

TY - JOUR

T1 - The [B3(NN)3]+ and [B3(CO)3]+ Complexes Featuring the Smallest π-Aromatic Species B3+

AU - Jin, Jiaye

AU - Wang, Guanjun

AU - Zhou, Mingfei

AU - Andrada, Diego M.

AU - Hermann, Markus

AU - Frenking, Gernot

PY - 2016/2/5

Y1 - 2016/2/5

N2 - We report the spectroscopic identification of the [B3(NN)3]+ and [B3(CO)3]+ complexes, which feature the smallest π-aromatic system B3+. A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3L2]+ σ-donation. Minimal π systems: The [B3(NN)3]+ and [B3(CO)3]+ complexes are identified through infrared photodissociation spectroscopy. The complexes feature the smallest π-aromatic system B3+. Quantum chemical bonding analysis reveals that the adducts are stabilized by L→[B3L2]+ σ-donation.

AB - We report the spectroscopic identification of the [B3(NN)3]+ and [B3(CO)3]+ complexes, which feature the smallest π-aromatic system B3+. A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3L2]+ σ-donation. Minimal π systems: The [B3(NN)3]+ and [B3(CO)3]+ complexes are identified through infrared photodissociation spectroscopy. The complexes feature the smallest π-aromatic system B3+. Quantum chemical bonding analysis reveals that the adducts are stabilized by L→[B3L2]+ σ-donation.

KW - aromaticity

KW - bonding analysis

KW - coordination chemistry

KW - photodissociation

KW - physical chemistry

UR - http://www.scopus.com/inward/record.url?scp=84957625107&partnerID=8YFLogxK

U2 - 10.1002/anie.201509826

DO - 10.1002/anie.201509826

M3 - 文章

AN - SCOPUS:84957625107

SN - 1433-7851

VL - 55

SP - 2078

EP - 2082

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 6

ER -

The [B₃(NN)₃]⁺ and [B₃(CO)₃]⁺ Complexes Featuring the Smallest π-Aromatic Species B₃⁺

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this