The influence of B2O3 on the microstructures and properties of CaO-B2O3-SiO2-Al 2O3 glass-ceramics (α-Al2O3) System

Hui Shao, Hong Qing Zhou, Xiao Dong Shen

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

3 Scopus citations

Abstract

The glass composition CaO-Al2O3-B2O 3-SiO2 as an alternative glass composition, and commercial α-Al2O3 as a ceramic material was used. The structure of the glass was analyzed by infrared spectra; the glass-ceramics thermal expansion coefficient was measured by dilatometer, the phase separation of the sample was investigated by scanning electron microscope and the component of phase was analyzed by X-ray. The results show that [BO3] increases and [BO4] decreases in the glass structure with the increasing of B2O3 content added into CaO-Al 2O3-B2O3-SiO2 glass. The relative density and dielectric constant (εr) are considerably decreased with the addition of amount of B2O3. Excellent microwave dielectric properties of 1MHz, εr = 8.0 and tanδ=0.003 are obtained by adding 10 wt% B2O3 to glass-ceramic and sintering at 875°Cfor 30 min.

Original languageEnglish
Title of host publicationManufacturing Process Technology
Pages4466-4471
Number of pages6
DOIs
StatePublished - 2011
Event2nd International Conference on Manufacturing Science and Engineering, ICMSE 2011 - Guilin, China
Duration: 9 Apr 201111 Apr 2011

Publication series

NameAdvanced Materials Research
Volume189-193
ISSN (Print)1022-6680

Conference

Conference2nd International Conference on Manufacturing Science and Engineering, ICMSE 2011
Country/TerritoryChina
CityGuilin
Period9/04/1111/04/11

Keywords

  • CaO-BO-SiO -AlO
  • Infrared spectra
  • LTCC
  • Microwave properties

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