The Oxygen-Rich Beryllium Oxides BeO4and BeO6

Qingnan Zhang; Paul Jerabek; Mohua Chen; Mingfei Zhou; Gernot Frenking

doi:10.1002/anie.201606154

The Oxygen-Rich Beryllium Oxides BeO₄and BeO₆

Qingnan Zhang, Paul Jerabek, Mohua Chen, Mingfei Zhou, Gernot Frenking

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Two novel isomers of BeO₄with the structures OBeOOO and OBe(O₃) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O₂)₂in solid noble-gas matrices. We also report the synthesis of the oxygen-rich bis(ozonide) complex Be(O₃)₂in the triplet state which has a D_2dequilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.

Original language	English
Pages (from-to)	10863-10867
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	36
DOIs	https://doi.org/10.1002/anie.201606154
State	Published - 26 Aug 2016
Externally published	Yes

Keywords

beryllium oxides
matrix isolation
ozonide complexes
quantum chemical calculations

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10.1002/anie.201606154

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title = "The Oxygen-Rich Beryllium Oxides BeO4and BeO6",

abstract = "Two novel isomers of BeO4with the structures OBeOOO and OBe(O3) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O2)2in solid noble-gas matrices. We also report the synthesis of the oxygen-rich bis(ozonide) complex Be(O3)2in the triplet state which has a D2dequilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.",

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author = "Qingnan Zhang and Paul Jerabek and Mohua Chen and Mingfei Zhou and Gernot Frenking",

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T1 - The Oxygen-Rich Beryllium Oxides BeO4and BeO6

AU - Zhang, Qingnan

AU - Jerabek, Paul

AU - Chen, Mohua

AU - Zhou, Mingfei

AU - Frenking, Gernot

PY - 2016/8/26

Y1 - 2016/8/26

N2 - Two novel isomers of BeO4with the structures OBeOOO and OBe(O3) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O2)2in solid noble-gas matrices. We also report the synthesis of the oxygen-rich bis(ozonide) complex Be(O3)2in the triplet state which has a D2dequilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.

AB - Two novel isomers of BeO4with the structures OBeOOO and OBe(O3) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O2)2in solid noble-gas matrices. We also report the synthesis of the oxygen-rich bis(ozonide) complex Be(O3)2in the triplet state which has a D2dequilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.

KW - beryllium oxides

KW - matrix isolation

KW - ozonide complexes

KW - quantum chemical calculations

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DO - 10.1002/anie.201606154

M3 - 文章

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EP - 10867

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

The Oxygen-Rich Beryllium Oxides BeO₄and BeO₆

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