TY - JOUR
T1 - The roles of rod-packed organic units for preparing stable porous coordination polymers with carboxylate ligands
AU - Duan, Jingui
AU - Jin, Wanqin
N1 - Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.
PY - 2015/11/9
Y1 - 2015/11/9
N2 - Despite tremendous efforts, designing and preparing water, chemical, and moisture stable porous coordination polymers (PCPs) with carboxylate ligands remain a challenge. Here, we firstly and systemically investigated the roles of rod-packed organic units for preparing the stable PCPs with different carboxylate ligands. The experimental results demonstrated that the rod packed organic units with short distance of adjacent ligands, bridged by La3 + metal chain, can form water, chemical, and moisture stable PCPs.
AB - Despite tremendous efforts, designing and preparing water, chemical, and moisture stable porous coordination polymers (PCPs) with carboxylate ligands remain a challenge. Here, we firstly and systemically investigated the roles of rod-packed organic units for preparing the stable PCPs with different carboxylate ligands. The experimental results demonstrated that the rod packed organic units with short distance of adjacent ligands, bridged by La3 + metal chain, can form water, chemical, and moisture stable PCPs.
KW - Adsorption
KW - La
KW - Porous coordination polymers
KW - Rod-packed organic units
KW - Stability
UR - http://www.scopus.com/inward/record.url?scp=84941089968&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2015.08.016
DO - 10.1016/j.inoche.2015.08.016
M3 - 文章
AN - SCOPUS:84941089968
SN - 1387-7003
VL - 61
SP - 53
EP - 56
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -