Thermally populated "bright" states for wide-range and high temperature sensing in air

Qiyun Fang; Jiewei Li; Shayu Li; Ruihong Duan; Shuangqing Wang; Yuanping Yi; Xudong Guo; Yan Qian; Wei Huang; Guoqiang Yang

doi:10.1039/c7cc00551b

Thermally populated "bright" states for wide-range and high temperature sensing in air

Qiyun Fang, Jiewei Li, Shayu Li, Ruihong Duan, Shuangqing Wang, Yuanping Yi, Xudong Guo, Yan Qian, Wei Huang, Guoqiang Yang

SCHOOL OF FLEXIBLE ELECTRONICS(FUTURE TECHNOLOGIES)|INSTITUTE OF ADVANCED MATERIALS(IAM)

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A series of air-stable triarylphosphine oxide-based thermosensitive ratiometric sensors based on local excited (LE) and charge transfer (CT) emissions have been designed and synthesized. The fluorescence intensity of tri(pyren-1-yl)phosphine oxide exhibits a prominent temperature-dependent feature over a wide temperature range due to thermally populated emissive LE states. The wide ratiometric temperature sensing range and high stability/reversibility in an ambient atmosphere indicate their great potentials in facile and practical applications.

Original language	English
Pages (from-to)	5702-5705
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	42
DOIs	https://doi.org/10.1039/c7cc00551b
State	Published - 2017

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title = "Thermally populated {"}bright{"} states for wide-range and high temperature sensing in air",

abstract = "A series of air-stable triarylphosphine oxide-based thermosensitive ratiometric sensors based on local excited (LE) and charge transfer (CT) emissions have been designed and synthesized. The fluorescence intensity of tri(pyren-1-yl)phosphine oxide exhibits a prominent temperature-dependent feature over a wide temperature range due to thermally populated emissive LE states. The wide ratiometric temperature sensing range and high stability/reversibility in an ambient atmosphere indicate their great potentials in facile and practical applications.",

author = "Qiyun Fang and Jiewei Li and Shayu Li and Ruihong Duan and Shuangqing Wang and Yuanping Yi and Xudong Guo and Yan Qian and Wei Huang and Guoqiang Yang",

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doi = "10.1039/c7cc00551b",

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T1 - Thermally populated "bright" states for wide-range and high temperature sensing in air

AU - Fang, Qiyun

AU - Li, Jiewei

AU - Li, Shayu

AU - Duan, Ruihong

AU - Wang, Shuangqing

AU - Yi, Yuanping

AU - Guo, Xudong

AU - Qian, Yan

AU - Huang, Wei

AU - Yang, Guoqiang

PY - 2017

Y1 - 2017

N2 - A series of air-stable triarylphosphine oxide-based thermosensitive ratiometric sensors based on local excited (LE) and charge transfer (CT) emissions have been designed and synthesized. The fluorescence intensity of tri(pyren-1-yl)phosphine oxide exhibits a prominent temperature-dependent feature over a wide temperature range due to thermally populated emissive LE states. The wide ratiometric temperature sensing range and high stability/reversibility in an ambient atmosphere indicate their great potentials in facile and practical applications.

AB - A series of air-stable triarylphosphine oxide-based thermosensitive ratiometric sensors based on local excited (LE) and charge transfer (CT) emissions have been designed and synthesized. The fluorescence intensity of tri(pyren-1-yl)phosphine oxide exhibits a prominent temperature-dependent feature over a wide temperature range due to thermally populated emissive LE states. The wide ratiometric temperature sensing range and high stability/reversibility in an ambient atmosphere indicate their great potentials in facile and practical applications.

UR - http://www.scopus.com/inward/record.url?scp=85018493464&partnerID=8YFLogxK

U2 - 10.1039/c7cc00551b

DO - 10.1039/c7cc00551b

M3 - 文章

C2 - 28286892

AN - SCOPUS:85018493464

SN - 1359-7345

VL - 53

SP - 5702

EP - 5705

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Thermally populated "bright" states for wide-range and high temperature sensing in air

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