Thermodynamic models for determination of the solid-liquid equilibrium of 2,5-thiophenedicarboxylic acid in (acetic acid+ethanol) binary solvent mixtures

Yonghong Hu; Yang Yang; Yang Cao; Yonglan Li; Wenge Yang; Limin Cheng

doi:10.1016/j.fluid.2015.06.007

Thermodynamic models for determination of the solid-liquid equilibrium of 2,5-thiophenedicarboxylic acid in (acetic acid+ethanol) binary solvent mixtures

Yonghong Hu, Yang Yang, Yang Cao, Yonglan Li, Wenge Yang, Limin Cheng

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In this work, the solid-liquid equilibrium (SLE) of 2,5-thiophenedicarboxylic acid in (acetic acid. +. ethanol) binary solvent mixtures was explored at temperatures ranging from 283.15. K to 328.15. K under atmosphere pressure. For the temperature range investigated, the equilibrium solubility varies with the composition of the solvent and temperature. The equilibrium solubility data were then modelled using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation and CNIBS/R-K model have the low MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.

Original language	English
Pages (from-to)	43-48
Number of pages	6
Journal	Fluid Phase Equilibria
Volume	403
DOIs	https://doi.org/10.1016/j.fluid.2015.06.007
State	Published - 5 Oct 2015

Keywords

2,5-Thiophenedicarboxylic acid
Apelblat equation
CNIBS/R-K
Jouyban-Acree model
Van't Hoff analysis

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10.1016/j.fluid.2015.06.007

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title = "Thermodynamic models for determination of the solid-liquid equilibrium of 2,5-thiophenedicarboxylic acid in (acetic acid+ethanol) binary solvent mixtures",

abstract = "In this work, the solid-liquid equilibrium (SLE) of 2,5-thiophenedicarboxylic acid in (acetic acid. +. ethanol) binary solvent mixtures was explored at temperatures ranging from 283.15. K to 328.15. K under atmosphere pressure. For the temperature range investigated, the equilibrium solubility varies with the composition of the solvent and temperature. The equilibrium solubility data were then modelled using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation and CNIBS/R-K model have the low MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.",

keywords = "2,5-Thiophenedicarboxylic acid, Apelblat equation, CNIBS/R-K, Jouyban-Acree model, Van't Hoff analysis",

author = "Yonghong Hu and Yang Yang and Yang Cao and Yonglan Li and Wenge Yang and Limin Cheng",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2015",

month = oct,

day = "5",

doi = "10.1016/j.fluid.2015.06.007",

language = "英语",

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T1 - Thermodynamic models for determination of the solid-liquid equilibrium of 2,5-thiophenedicarboxylic acid in (acetic acid+ethanol) binary solvent mixtures

AU - Hu, Yonghong

AU - Yang, Yang

AU - Cao, Yang

AU - Li, Yonglan

AU - Yang, Wenge

AU - Cheng, Limin

PY - 2015/10/5

Y1 - 2015/10/5

N2 - In this work, the solid-liquid equilibrium (SLE) of 2,5-thiophenedicarboxylic acid in (acetic acid. +. ethanol) binary solvent mixtures was explored at temperatures ranging from 283.15. K to 328.15. K under atmosphere pressure. For the temperature range investigated, the equilibrium solubility varies with the composition of the solvent and temperature. The equilibrium solubility data were then modelled using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation and CNIBS/R-K model have the low MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.

AB - In this work, the solid-liquid equilibrium (SLE) of 2,5-thiophenedicarboxylic acid in (acetic acid. +. ethanol) binary solvent mixtures was explored at temperatures ranging from 283.15. K to 328.15. K under atmosphere pressure. For the temperature range investigated, the equilibrium solubility varies with the composition of the solvent and temperature. The equilibrium solubility data were then modelled using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redlich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation and CNIBS/R-K model have the low MD (mean deviation). In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis.

KW - 2,5-Thiophenedicarboxylic acid

KW - Apelblat equation

KW - CNIBS/R-K

KW - Jouyban-Acree model

KW - Van't Hoff analysis

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U2 - 10.1016/j.fluid.2015.06.007

DO - 10.1016/j.fluid.2015.06.007

M3 - 文章

AN - SCOPUS:84931273745

SN - 0378-3812

VL - 403

SP - 43

EP - 48

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

ER -

Thermodynamic models for determination of the solid-liquid equilibrium of 2,5-thiophenedicarboxylic acid in (acetic acid+ethanol) binary solvent mixtures

Abstract

Keywords

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