Three polynuclear complexes with bridging triazole ligand: Crystal structures

Lei Shen; Qiu Jie Xia; Lei Wang; Jie Yang; Yong Chen; Xiao Yan Tang; Yun Sheng Ma; Rong Xin Yuan; Dun Ru Zhu

doi:10.1080/00958972.2014.927060

Three polynuclear complexes with bridging triazole ligand: Crystal structures

Lei Shen, Qiu Jie Xia, Lei Wang, Jie Yang, Yong Chen, Xiao Yan Tang, Yun Sheng Ma, Rong Xin Yuan, Dun Ru Zhu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Three polynuclear clusters, [Cu₄L₈](ClO ₄)₄·4H₂O (1), [Zn₃L ₆(H₂O)₆](ClO₄)₆· 6H₂O (2), and [Mn₃L₆(CH₃OH) ₆](ClO₄)₆·4.5H₂O (3) (L = 4-(4-hydroxyphenyl)-1,2,4-triazole), obtained by the reactions of M(ClO ₄)₂·6H₂O with L have been isolated and structurally characterized. Complex 1 featured a tetranuclear Cu(I) structure. Both 2 and 3 are linear hexapositive trimers linked by three N1,N2-1,2,4-triazole ligands to the divalent central and terminal metal ions. Furthermore, the luminescence properties of 2 were investigated at room temperature in the solid state.

Original language	English
Pages (from-to)	1573-1583
Number of pages	11
Journal	Journal of Coordination Chemistry
Volume	67
Issue number	9
DOIs	https://doi.org/10.1080/00958972.2014.927060
State	Published - 3 May 2014

Keywords

Cluster
Copper(I)
Luminescence
Manganese(II)
Polynuclear complex
Zinc(II)

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10.1080/00958972.2014.927060

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@article{b7d92b8eca91494d8365aefeaed44502,

title = "Three polynuclear complexes with bridging triazole ligand: Crystal structures",

abstract = "Three polynuclear clusters, [Cu4L8](ClO 4)4·4H2O (1), [Zn3L 6(H2O)6](ClO4)6· 6H2O (2), and [Mn3L6(CH3OH) 6](ClO4)6·4.5H2O (3) (L = 4-(4-hydroxyphenyl)-1,2,4-triazole), obtained by the reactions of M(ClO 4)2·6H2O with L have been isolated and structurally characterized. Complex 1 featured a tetranuclear Cu(I) structure. Both 2 and 3 are linear hexapositive trimers linked by three N1,N2-1,2,4-triazole ligands to the divalent central and terminal metal ions. Furthermore, the luminescence properties of 2 were investigated at room temperature in the solid state.",

keywords = "Cluster, Copper(I), Luminescence, Manganese(II), Polynuclear complex, Zinc(II)",

author = "Lei Shen and Xia, {Qiu Jie} and Lei Wang and Jie Yang and Yong Chen and Tang, {Xiao Yan} and Ma, {Yun Sheng} and Yuan, {Rong Xin} and Zhu, {Dun Ru}",

year = "2014",

month = may,

day = "3",

doi = "10.1080/00958972.2014.927060",

language = "英语",

volume = "67",

pages = "1573--1583",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "9",

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TY - JOUR

T1 - Three polynuclear complexes with bridging triazole ligand

T2 - Crystal structures

AU - Shen, Lei

AU - Xia, Qiu Jie

AU - Wang, Lei

AU - Yang, Jie

AU - Chen, Yong

AU - Tang, Xiao Yan

AU - Ma, Yun Sheng

AU - Yuan, Rong Xin

AU - Zhu, Dun Ru

PY - 2014/5/3

Y1 - 2014/5/3

N2 - Three polynuclear clusters, [Cu4L8](ClO 4)4·4H2O (1), [Zn3L 6(H2O)6](ClO4)6· 6H2O (2), and [Mn3L6(CH3OH) 6](ClO4)6·4.5H2O (3) (L = 4-(4-hydroxyphenyl)-1,2,4-triazole), obtained by the reactions of M(ClO 4)2·6H2O with L have been isolated and structurally characterized. Complex 1 featured a tetranuclear Cu(I) structure. Both 2 and 3 are linear hexapositive trimers linked by three N1,N2-1,2,4-triazole ligands to the divalent central and terminal metal ions. Furthermore, the luminescence properties of 2 were investigated at room temperature in the solid state.

AB - Three polynuclear clusters, [Cu4L8](ClO 4)4·4H2O (1), [Zn3L 6(H2O)6](ClO4)6· 6H2O (2), and [Mn3L6(CH3OH) 6](ClO4)6·4.5H2O (3) (L = 4-(4-hydroxyphenyl)-1,2,4-triazole), obtained by the reactions of M(ClO 4)2·6H2O with L have been isolated and structurally characterized. Complex 1 featured a tetranuclear Cu(I) structure. Both 2 and 3 are linear hexapositive trimers linked by three N1,N2-1,2,4-triazole ligands to the divalent central and terminal metal ions. Furthermore, the luminescence properties of 2 were investigated at room temperature in the solid state.

KW - Cluster

KW - Copper(I)

KW - Luminescence

KW - Manganese(II)

KW - Polynuclear complex

KW - Zinc(II)

UR - http://www.scopus.com/inward/record.url?scp=84903581867&partnerID=8YFLogxK

U2 - 10.1080/00958972.2014.927060

DO - 10.1080/00958972.2014.927060

M3 - 文章

AN - SCOPUS:84903581867

SN - 0095-8972

VL - 67

SP - 1573

EP - 1583

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 9

ER -

Three polynuclear complexes with bridging triazole ligand: Crystal structures

Abstract

Keywords

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