TY - JOUR
T1 - Trans-methyl-azido-bis(triisopropylphosphin)platin(ii), [PtN3(CH3)PiPr3)2]
AU - Schlecht, Sabine
AU - Faza, Naim
AU - Massa, Werner
AU - Dapprich, Stefan
AU - Frenking, Gernot
AU - Dehnicke, Kurt
PY - 1998
Y1 - 1998
N2 - [PtN3(CH3)(PiPr3)2] has been prepared by reductive elimination of ethane from [Pt(CH3)3N3]4 in the presence of triisopropylphosphine at 80°C. The complex is characterized by IR and NMR spectroscopy and by crystal structure determination, as well as by ab initio calculations. [PtN3(CH3)(PiPr3)2], which is in trans-configuration here, crystallizes in the monoclinic space group P21, Z = 2, and with the lattice dimensions a = 806.9(1), b = 1384.3(1), c = 1093.8(1) pm, β = 94.107(10)°.
AB - [PtN3(CH3)(PiPr3)2] has been prepared by reductive elimination of ethane from [Pt(CH3)3N3]4 in the presence of triisopropylphosphine at 80°C. The complex is characterized by IR and NMR spectroscopy and by crystal structure determination, as well as by ab initio calculations. [PtN3(CH3)(PiPr3)2], which is in trans-configuration here, crystallizes in the monoclinic space group P21, Z = 2, and with the lattice dimensions a = 806.9(1), b = 1384.3(1), c = 1093.8(1) pm, β = 94.107(10)°.
KW - Ab initio calculations
KW - Crystal structure
KW - Methyl-azido complex of platinum
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=0032362301&partnerID=8YFLogxK
U2 - 10.1002/(sici)1521-3749(199806)624:6<1011::aid-zaac1011>3.0.co;2-m
DO - 10.1002/(sici)1521-3749(199806)624:6<1011::aid-zaac1011>3.0.co;2-m
M3 - 文章
AN - SCOPUS:0032362301
SN - 0044-2313
VL - 624
SP - 1011
EP - 1014
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 6
ER -