Two d10 coordination polymers based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties

Guang Xiang Liu; Heng Xu; Xiao Ming Ren; Sadafumi Nishihara; Yan Wang

doi:10.1016/j.inoche.2009.04.010

Two d¹⁰ coordination polymers based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties

Guang Xiang Liu, Heng Xu, Xiao Ming Ren, Sadafumi Nishihara, Yan Wang

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two novel coordination polymers, [Zn₂(FA)(4,4′-bipy)₂]·2H₂O (1) and Cd₂(FA)(2,2′-bipy) (2), (H₄FA = 4,4′-(hexafluoroisopropylidene)diphthalic acid, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine), have been synthesized under hydrothermal conditions, and their structures were determined by single-crystal X-ray diffraction. Polymer 1 features an unusual three-dimensional (3D) network with (4 · 6² · 8³)(4² · 6² · 8²) topology. Polymer 2 has a complicated 3D framework and crystallizes in non-centrosymmetric space group (Fdd2) belonging to polar point group (C_2v), which displays a strong SHG response and ferroelectric properties. Moreover, the luminescent properties of 1 and 2 have also been investigated.

Original language	English
Pages (from-to)	498-501
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2009.04.010
State	Published - Jun 2009
Externally published	Yes

Keywords

Ferroelectricity
Luminescence
Metal-organic framework
Topology

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@article{b715527caa59401291e64ab14e138662,

title = "Two d10 coordination polymers based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties",

abstract = "Two novel coordination polymers, [Zn2(FA)(4,4′-bipy)2]·2H2O (1) and Cd2(FA)(2,2′-bipy) (2), (H4FA = 4,4′-(hexafluoroisopropylidene)diphthalic acid, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine), have been synthesized under hydrothermal conditions, and their structures were determined by single-crystal X-ray diffraction. Polymer 1 features an unusual three-dimensional (3D) network with (4 · 62 · 83)(42 · 62 · 82) topology. Polymer 2 has a complicated 3D framework and crystallizes in non-centrosymmetric space group (Fdd2) belonging to polar point group (C2v), which displays a strong SHG response and ferroelectric properties. Moreover, the luminescent properties of 1 and 2 have also been investigated.",

keywords = "Ferroelectricity, Luminescence, Metal-organic framework, Topology",

author = "Liu, {Guang Xiang} and Heng Xu and Ren, {Xiao Ming} and Sadafumi Nishihara and Yan Wang",

year = "2009",

month = jun,

doi = "10.1016/j.inoche.2009.04.010",

language = "英语",

volume = "12",

pages = "498--501",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

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T1 - Two d10 coordination polymers based on 4,4′-(hexafluoroisopropylidene)diphthalic acid

T2 - Syntheses, structures and physical properties

AU - Liu, Guang Xiang

AU - Xu, Heng

AU - Ren, Xiao Ming

AU - Nishihara, Sadafumi

AU - Wang, Yan

PY - 2009/6

Y1 - 2009/6

N2 - Two novel coordination polymers, [Zn2(FA)(4,4′-bipy)2]·2H2O (1) and Cd2(FA)(2,2′-bipy) (2), (H4FA = 4,4′-(hexafluoroisopropylidene)diphthalic acid, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine), have been synthesized under hydrothermal conditions, and their structures were determined by single-crystal X-ray diffraction. Polymer 1 features an unusual three-dimensional (3D) network with (4 · 62 · 83)(42 · 62 · 82) topology. Polymer 2 has a complicated 3D framework and crystallizes in non-centrosymmetric space group (Fdd2) belonging to polar point group (C2v), which displays a strong SHG response and ferroelectric properties. Moreover, the luminescent properties of 1 and 2 have also been investigated.

AB - Two novel coordination polymers, [Zn2(FA)(4,4′-bipy)2]·2H2O (1) and Cd2(FA)(2,2′-bipy) (2), (H4FA = 4,4′-(hexafluoroisopropylidene)diphthalic acid, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine), have been synthesized under hydrothermal conditions, and their structures were determined by single-crystal X-ray diffraction. Polymer 1 features an unusual three-dimensional (3D) network with (4 · 62 · 83)(42 · 62 · 82) topology. Polymer 2 has a complicated 3D framework and crystallizes in non-centrosymmetric space group (Fdd2) belonging to polar point group (C2v), which displays a strong SHG response and ferroelectric properties. Moreover, the luminescent properties of 1 and 2 have also been investigated.

KW - Ferroelectricity

KW - Luminescence

KW - Metal-organic framework

KW - Topology

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U2 - 10.1016/j.inoche.2009.04.010

DO - 10.1016/j.inoche.2009.04.010

M3 - 文章

AN - SCOPUS:67349105370

SN - 1387-7003

VL - 12

SP - 498

EP - 501

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Two d¹⁰ coordination polymers based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Syntheses, structures and physical properties

Abstract

Keywords

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