Two {Mo 36}-containing polymolybdates: Synthesis, crystal structures, and spectral characterizations

Zhangang Han; Wenbo Pei; Jingli Xie; Yang Zou; Xiao Ming Ren

doi:10.1016/j.inoche.2011.11.031

Two {Mo ₃₆}-containing polymolybdates: Synthesis, crystal structures, and spectral characterizations

Zhangang Han, Wenbo Pei, Jingli Xie, Yang Zou, Xiao Ming Ren

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Two polyanion clusters [Mo ₃₆O ₁₀₈(NO) ₄(H ₂O) ₁₆] ^{12 -} (1) and [Mo ₃₆O ₁₁₂(H ₂O) ₁₆Cu _0.5(H ₂O) ₂] ^{7 -} (2) were obtained through 'one-pot' reaction at ambient temperature and pressure. Both of 1 and 2 consist of {Mo ₃₆} anionic clusters. Interestingly, compound 2 represents a case that the transitional metal copper is anchored into the framework of a giant {Mo ₃₆} isopolyanion.

Original language	English
Pages (from-to)	61-64
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	16
DOIs	https://doi.org/10.1016/j.inoche.2011.11.031
State	Published - Feb 2012

Keywords

Coordination geometry
Copper
High-core cluster
Polyoxometalate

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10.1016/j.inoche.2011.11.031

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title = "Two {Mo 36}-containing polymolybdates: Synthesis, crystal structures, and spectral characterizations",

abstract = "Two polyanion clusters [Mo 36O 108(NO) 4(H 2O) 16] 12 - (1) and [Mo 36O 112(H 2O) 16Cu 0.5(H 2O) 2] 7 - (2) were obtained through 'one-pot' reaction at ambient temperature and pressure. Both of 1 and 2 consist of {Mo 36} anionic clusters. Interestingly, compound 2 represents a case that the transitional metal copper is anchored into the framework of a giant {Mo 36} isopolyanion.",

keywords = "Coordination geometry, Copper, High-core cluster, Polyoxometalate",

author = "Zhangang Han and Wenbo Pei and Jingli Xie and Yang Zou and Ren, {Xiao Ming}",

year = "2012",

month = feb,

doi = "10.1016/j.inoche.2011.11.031",

language = "英语",

volume = "16",

pages = "61--64",

journal = "Inorganic Chemistry Communications",

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T1 - Two {Mo 36}-containing polymolybdates

T2 - Synthesis, crystal structures, and spectral characterizations

AU - Han, Zhangang

AU - Pei, Wenbo

AU - Xie, Jingli

AU - Zou, Yang

AU - Ren, Xiao Ming

PY - 2012/2

Y1 - 2012/2

N2 - Two polyanion clusters [Mo 36O 108(NO) 4(H 2O) 16] 12 - (1) and [Mo 36O 112(H 2O) 16Cu 0.5(H 2O) 2] 7 - (2) were obtained through 'one-pot' reaction at ambient temperature and pressure. Both of 1 and 2 consist of {Mo 36} anionic clusters. Interestingly, compound 2 represents a case that the transitional metal copper is anchored into the framework of a giant {Mo 36} isopolyanion.

AB - Two polyanion clusters [Mo 36O 108(NO) 4(H 2O) 16] 12 - (1) and [Mo 36O 112(H 2O) 16Cu 0.5(H 2O) 2] 7 - (2) were obtained through 'one-pot' reaction at ambient temperature and pressure. Both of 1 and 2 consist of {Mo 36} anionic clusters. Interestingly, compound 2 represents a case that the transitional metal copper is anchored into the framework of a giant {Mo 36} isopolyanion.

KW - Coordination geometry

KW - Copper

KW - High-core cluster

KW - Polyoxometalate

UR - http://www.scopus.com/inward/record.url?scp=84855700962&partnerID=8YFLogxK

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DO - 10.1016/j.inoche.2011.11.031

M3 - 文章

AN - SCOPUS:84855700962

SN - 1387-7003

VL - 16

SP - 61

EP - 64

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Two {Mo ₃₆}-containing polymolybdates: Synthesis, crystal structures, and spectral characterizations

Abstract

Keywords

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