Two new self-assemblies of two zinc porphyrin with isonicotinic acid by metal-ligand axial coordination and their applications in supramolecular solar cell

Jing Cao; Jia Cheng Liu; Li Wei Chen; Ren Zhi Li; Neng Zhi Jin

doi:10.1016/j.tetlet.2013.05.043

Two new self-assemblies of two zinc porphyrin with isonicotinic acid by metal-ligand axial coordination and their applications in supramolecular solar cell

Jing Cao, Jia Cheng Liu, Li Wei Chen, Ren Zhi Li, Neng Zhi Jin

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Two new self-assemblies based on two zinc porphyrins substituted at the meso-positions with different donor units (denoted as ZnP1 and ZnP2) and isonicotinic acid (A) by metal-ligand axial coordination have been designed and immobilized on the double-layer nanostructured TiO₂ film-coated highly transparent FTO conducting glass electrode in a photosynthesis device. These cells were also measured under irradiance of 100 mW cm^-2 AM 1.5G sunlight. The results reveal that the performance of ZnP2-A outperforms that of ZnP1-A. The UV-vis absorption spectra, fluorescence spectra, molecular orbital (MO) patterns, and HOMO-LUMO energy gaps of these assemblies were also investigated to further demonstrate the photovoltaic behavior of these cells.

Original language	English
Pages (from-to)	3851-3854
Number of pages	4
Journal	Tetrahedron Letters
Volume	54
Issue number	29
DOIs	https://doi.org/10.1016/j.tetlet.2013.05.043
State	Published - 17 Jul 2013
Externally published	Yes

Keywords

Self-assembly
Solar cell
Zinc porphyrin

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.tetlet.2013.05.043

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title = "Two new self-assemblies of two zinc porphyrin with isonicotinic acid by metal-ligand axial coordination and their applications in supramolecular solar cell",

abstract = "Two new self-assemblies based on two zinc porphyrins substituted at the meso-positions with different donor units (denoted as ZnP1 and ZnP2) and isonicotinic acid (A) by metal-ligand axial coordination have been designed and immobilized on the double-layer nanostructured TiO2 film-coated highly transparent FTO conducting glass electrode in a photosynthesis device. These cells were also measured under irradiance of 100 mW cm-2 AM 1.5G sunlight. The results reveal that the performance of ZnP2-A outperforms that of ZnP1-A. The UV-vis absorption spectra, fluorescence spectra, molecular orbital (MO) patterns, and HOMO-LUMO energy gaps of these assemblies were also investigated to further demonstrate the photovoltaic behavior of these cells.",

keywords = "Self-assembly, Solar cell, Zinc porphyrin",

author = "Jing Cao and Liu, {Jia Cheng} and Chen, {Li Wei} and Li, {Ren Zhi} and Jin, {Neng Zhi}",

year = "2013",

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day = "17",

doi = "10.1016/j.tetlet.2013.05.043",

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pages = "3851--3854",

journal = "Tetrahedron Letters",

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T1 - Two new self-assemblies of two zinc porphyrin with isonicotinic acid by metal-ligand axial coordination and their applications in supramolecular solar cell

AU - Cao, Jing

AU - Liu, Jia Cheng

AU - Chen, Li Wei

AU - Li, Ren Zhi

AU - Jin, Neng Zhi

PY - 2013/7/17

Y1 - 2013/7/17

N2 - Two new self-assemblies based on two zinc porphyrins substituted at the meso-positions with different donor units (denoted as ZnP1 and ZnP2) and isonicotinic acid (A) by metal-ligand axial coordination have been designed and immobilized on the double-layer nanostructured TiO2 film-coated highly transparent FTO conducting glass electrode in a photosynthesis device. These cells were also measured under irradiance of 100 mW cm-2 AM 1.5G sunlight. The results reveal that the performance of ZnP2-A outperforms that of ZnP1-A. The UV-vis absorption spectra, fluorescence spectra, molecular orbital (MO) patterns, and HOMO-LUMO energy gaps of these assemblies were also investigated to further demonstrate the photovoltaic behavior of these cells.

AB - Two new self-assemblies based on two zinc porphyrins substituted at the meso-positions with different donor units (denoted as ZnP1 and ZnP2) and isonicotinic acid (A) by metal-ligand axial coordination have been designed and immobilized on the double-layer nanostructured TiO2 film-coated highly transparent FTO conducting glass electrode in a photosynthesis device. These cells were also measured under irradiance of 100 mW cm-2 AM 1.5G sunlight. The results reveal that the performance of ZnP2-A outperforms that of ZnP1-A. The UV-vis absorption spectra, fluorescence spectra, molecular orbital (MO) patterns, and HOMO-LUMO energy gaps of these assemblies were also investigated to further demonstrate the photovoltaic behavior of these cells.

KW - Self-assembly

KW - Solar cell

KW - Zinc porphyrin

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DO - 10.1016/j.tetlet.2013.05.043

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Two new self-assemblies of two zinc porphyrin with isonicotinic acid by metal-ligand axial coordination and their applications in supramolecular solar cell

Abstract

Keywords

UN SDGs

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