Two new three-dimensional porous polyoxometalates with typical ACO topological open frameworks: {[Cu4v13IVv 5vO42(NO3)(C3H 10N2)8]·10H2O}n

Yan Xu; Lin Bo Nie; Dunru Zhu; You Song; Guang Peng Zhou; Wan Sheng You

doi:10.1021/cg0607912

Two new three-dimensional porous polyoxometalates with typical ACO topological open frameworks: {[Cu₄v₁₃^IVv ₅^vO₄₂(NO₃)(C₃H ₁₀N₂)₈]·10H₂O}_n

Yan Xu, Lin Bo Nie, Dunru Zhu, You Song, Guang Peng Zhou, Wan Sheng You

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

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Abstract

Two new three-dimensional open frameworks, {[Cu₄V ₁₃^IVV₅^VO₄₂(NO ₃)(C₃H₁₀N₂)₈] ·10H₂O}_n (1) and {[Cu₄V ₁₂^IVV₆^VO₄₂-(SO ₄)(C₃H₁₀N₂)₈] ·10H₂O}_n (2), have been hydrothermally synthesized. Structural analysis indicates that both complexes are isomorphic and are constructed from a cluster anion [V₁₈O₄₂(XO _y)]^8- (X = N, y = 3 or X = S, y = 4) and a bridging cation [Cu(C₃H₁₀N₂)₂]²⁺ with classical ACO topological structure. Complex 1 crystallizes in the tetragonal space group P4/nnc, with a = b = 15.1128(12) Å, c = 18.670(3) Å, V = 4264.1(9) Å³, Z = 2. Complex 2 is tetragonal, P4/nnc, a = b= 15.1131(10) Å, c = 18.588(10) Å, V = 4245.5(7) Å³, Z = 2. Both complexes keep the same topological framework with channels of dimensions 7.5 × 7.5 Å running along the [001] direction.

Original language	English
Pages (from-to)	925-929
Number of pages	5
Journal	Crystal Growth and Design
Volume	7
Issue number	5
DOIs	https://doi.org/10.1021/cg0607912
State	Published - May 2007

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@article{72027201c71a43ae898d2fa5678f7825,

title = "Two new three-dimensional porous polyoxometalates with typical ACO topological open frameworks: {[Cu4v13IVv 5vO42(NO3)(C3H 10N2)8]·10H2O}n",

abstract = "Two new three-dimensional open frameworks, {[Cu4V 13IVV5VO42(NO 3)(C3H10N2)8] ·10H2O}n (1) and {[Cu4V 12IVV6VO42-(SO 4)(C3H10N2)8] ·10H2O}n (2), have been hydrothermally synthesized. Structural analysis indicates that both complexes are isomorphic and are constructed from a cluster anion [V18O42(XO y)]8- (X = N, y = 3 or X = S, y = 4) and a bridging cation [Cu(C3H10N2)2]2+ with classical ACO topological structure. Complex 1 crystallizes in the tetragonal space group P4/nnc, with a = b = 15.1128(12) {\AA}, c = 18.670(3) {\AA}, V = 4264.1(9) {\AA}3, Z = 2. Complex 2 is tetragonal, P4/nnc, a = b= 15.1131(10) {\AA}, c = 18.588(10) {\AA}, V = 4245.5(7) {\AA}3, Z = 2. Both complexes keep the same topological framework with channels of dimensions 7.5 × 7.5 {\AA} running along the [001] direction.",

author = "Yan Xu and Nie, {Lin Bo} and Dunru Zhu and You Song and Zhou, {Guang Peng} and You, {Wan Sheng}",

year = "2007",

month = may,

doi = "10.1021/cg0607912",

language = "英语",

volume = "7",

pages = "925--929",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Two new three-dimensional porous polyoxometalates with typical ACO topological open frameworks

T2 - {[Cu4v13IVv 5vO42(NO3)(C3H 10N2)8]·10H2O}n

AU - Xu, Yan

AU - Nie, Lin Bo

AU - Zhu, Dunru

AU - Song, You

AU - Zhou, Guang Peng

AU - You, Wan Sheng

PY - 2007/5

Y1 - 2007/5

N2 - Two new three-dimensional open frameworks, {[Cu4V 13IVV5VO42(NO 3)(C3H10N2)8] ·10H2O}n (1) and {[Cu4V 12IVV6VO42-(SO 4)(C3H10N2)8] ·10H2O}n (2), have been hydrothermally synthesized. Structural analysis indicates that both complexes are isomorphic and are constructed from a cluster anion [V18O42(XO y)]8- (X = N, y = 3 or X = S, y = 4) and a bridging cation [Cu(C3H10N2)2]2+ with classical ACO topological structure. Complex 1 crystallizes in the tetragonal space group P4/nnc, with a = b = 15.1128(12) Å, c = 18.670(3) Å, V = 4264.1(9) Å3, Z = 2. Complex 2 is tetragonal, P4/nnc, a = b= 15.1131(10) Å, c = 18.588(10) Å, V = 4245.5(7) Å3, Z = 2. Both complexes keep the same topological framework with channels of dimensions 7.5 × 7.5 Å running along the [001] direction.

AB - Two new three-dimensional open frameworks, {[Cu4V 13IVV5VO42(NO 3)(C3H10N2)8] ·10H2O}n (1) and {[Cu4V 12IVV6VO42-(SO 4)(C3H10N2)8] ·10H2O}n (2), have been hydrothermally synthesized. Structural analysis indicates that both complexes are isomorphic and are constructed from a cluster anion [V18O42(XO y)]8- (X = N, y = 3 or X = S, y = 4) and a bridging cation [Cu(C3H10N2)2]2+ with classical ACO topological structure. Complex 1 crystallizes in the tetragonal space group P4/nnc, with a = b = 15.1128(12) Å, c = 18.670(3) Å, V = 4264.1(9) Å3, Z = 2. Complex 2 is tetragonal, P4/nnc, a = b= 15.1131(10) Å, c = 18.588(10) Å, V = 4245.5(7) Å3, Z = 2. Both complexes keep the same topological framework with channels of dimensions 7.5 × 7.5 Å running along the [001] direction.

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U2 - 10.1021/cg0607912

DO - 10.1021/cg0607912

M3 - 文章

AN - SCOPUS:34249079204

SN - 1528-7483

VL - 7

SP - 925

EP - 929

JO - Crystal Growth and Design

JF - Crystal Growth and Design

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ER -

Two new three-dimensional porous polyoxometalates with typical ACO topological open frameworks: {[Cu₄v₁₃^IVv ₅^vO₄₂(NO₃)(C₃H ₁₀N₂)₈]·10H₂O}_n

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