Visible-light-initiated regio- and stereoselective C(sp2)-H phosphorylation of enamides under transition-metal-free conditions

Ji Yu Tao, Qing Hong Zhang, Tong Hao Zhu, Xin Wen Xu, Kun Ni, Qiao Zhao, Zheng Bao Qin, Yu Zhang, Lili Zhao, Kai Zhao

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A visible-light-induced stereo- and regioselective phosphorylation reaction of enamides with phosphine oxides has been disclosed, delivering synthetically and pharmaceutically appealing β-phosphorylated enamides with broad substrate scopes and excellent functional group tolerance under transition-metal-free conditions.

Original languageEnglish
Pages (from-to)6540-6546
Number of pages7
JournalOrganic Chemistry Frontiers
Volume9
Issue number23
DOIs
StatePublished - 7 Oct 2022

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